Palladium-Catalyzed Allenamide Carbopalladation/Allylation with Active Methine Compounds
2021
Zhu, Xiaoyi | Li, Ruibo | Yao, Hequan | Lin, Aijun
A palladium-catalyzed allenamide carbopalladation/allylation with active methine compounds has been developed. Various indoles and isoquinolinones bearing a quaternary carbon center were achieved with good efficiency, a broad substrate scope and good functional group tolerance. This reaction underwent cascade oxidative addition, carbopalladation, and allylic alkylation, and two new C–C bonds were formed in one pot.
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