Nutrient and Antioxidant Properties of Oils from Bagasses, Agricultural Residues, Medicinal Plants, and Fodders
2019
Nnabugwu, Agomuo Emmanuel | Uchenna, Amadi Peter
Objective: This study evaluated the physicochemical properties, fatty acid (FA) and phytochemical compositions, and free radical–scavenging potentials of oils from the bagasses: Costus afer stem (CA) and Saccharum officinarum stem (SB); agricultural residues; corn cobs (CC); tigernut chaff (TB); peanut hulls (GH); medicinal plants: Sphenocentrum jollyanum leaves (SJ) and Senna alata leaves (CS); and fodders: Pennisetum purpureum (PP), Panicum maximum (PM), and Chloris gayana stalks (CG). Method: Oils from the samples were extracted using a mixture of n-hexane and isopropyl alcohol (3:2). The oils were analyzed for physicochemical properties using standard procedures, phytochemicals and FAs contents using gas chromatography-fluorescent ionization detection, and free radical–scavenging potentials using spectrophotometric methods of determination. Results: The bagasse and residue oils contained lower moisture contents (1.13%–2.38%) and acid values (1.89–9.20 mg/KOH/g), while the GH oil produced the least refractive indices, saponification value, and oil yield. CA oil contained 78% saturated FA, while SB oils contained 73.65% saturated FA and an abundance of lignoceric, palmitoleic, oleic, and arachidic acid. CC oil contained mostly behenic acid (19.65%), and GH oil produced 87.04% saturated FA, while TB oil produced 56% unsaturated FA. Oils from SJ, CS, PP, PM, and CG contained between 48.34% and 57.09% unsaturated FA. The phytochemical composition showed that ribalinidine and sapogenin were most abundant in PM oil, while lunamarine, kaempferol, and catechin were most abundant in SJ oil. GH oil produced the highest amounts of phytate (53.81 µg/ml) and oxalate (39.47 µg/ml). TB oil and oils from SJ and CS, especially at higher concentrations, matched the scavenging potentials of the standards used. Conclusions: Due to the thermal stability and amount of short chain fatty acids (SFAs) of the SB, CA, CC, and GH oils, they are more suitable for non-food industrial purposes, while TB, SJ, and CS oil properties are recommendable for therapeutic purposes, especially for relief of oxidative stress.
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