N-Acylimino-λ³-iodanes from the Metathesis of Iodosoarenes and Nitriles for the Photoinduced C–H Perfluoroacylamination of (Hetero)Arenes
2022
Kimura, Tomohiro | Hamada, Shohei | Furuta, Takumi | Takemoto, Yoshiji | Kobayashi, Yūsuke
An efficient and scalable synthesis of N-perfluoroacylimino-λ³-iodanes was achieved via an unprecedented metathesis between iodosoarenes and perfluoroalkanenitriles. The perfluoroacylamino groups of the iodanes could be introduced to aromatic and heteroaromatic rings using photoirradiation.
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