Esterification of carboxylic acids by tributyl borate under solvent- and catalyst-free conditions
2005
Mansoori, Yagoub | Tataroglu, Firdovsi Seyidov | Sadaghian, Mitra
A new method for esterification of mono- and dicarboxylic acids by tributyl borate has been reported. The esterification reactions have been cleanly carried out in the absence of any solvent under catalyst-free conditions. Boric acid is the only side product, which precipitates during the reaction and can be re-used in the production of tributyl borate. Important mono- and dibutylesters, which have found wide applications as plasticizers and ester base lubricants, were prepared by this manner.
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