Total Synthesis of Sandresolide B and Amphilectolide
2014
Chen, Ingrid T. | Baitinger, Irina | Schreyer, Lucas | Trauner, Dirk
The total synthesis of the diterpenoids sandresolide B and amphilectolide from a common furan building block is presented. Key steps include palladium-mediated carbonylation, lanthanide catalyzed ring closure, Myers alkylation, intramolecular Friedel–Crafts acylation, photooxygenation, and a Kornblum–DeLaMare rearrangement.
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