Synthesis of acetamides using CO₂, methanol, H₂ and amines
2019
Zhang, Jingjing | Qian, Qingli | Wang, Ying | Asare Bediako, Bernard Baffour | Cui, Meng | Yang, Guanying | Han, Buxing
Herein, we report the synthesis of acetamides from CO₂, methanol, H₂ and corresponding amines, which is a new route used to synthesize acetamides. It was found that the Rh catalyst with LiI/LiCl as promoters could effectively catalyze this reaction. Interestingly, no ligand was required and amine substrates played a role in accelerating the reaction.
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Эту запись предоставил National Agricultural Library