Degradation of naproxen in chlorination and UV/chlorine processes: kinetics and degradation products

Liu, Yongze; Tang, Yuqing; Wu, Yongxin; Feng, Li; Zhang, Liqiu

Degradation of naproxen in chlorination and UV/chlorine processes: kinetics and degradation products

2019

Liu, Yongze | Tang, Yuqing | Wu, Yongxin | Feng, Li | Zhang, Liqiu

Naproxen (NAP) is a nonsteroidal anti-inflammatory drug which has been widely used and frequently detected in water environments. This study investigated the NAP degradation in the chlorination and UV/chlorine disinfection processes, which usually acted as the last barriers for water treatment. The results showed that both chlorination and UV/chlorine disinfection could remove NAP effectively. At various chlorine dosages (0.1~0.5 mM), the contributions of chlorination and reactive radicals to the degradation of NAP in the UV/chlorine process were calculated to be 50.5~56.9% and 43.1~49.5%, respectively. However, the reactive radicals dominated in NAP degradation in alkaline solutions, while chlorination dominated in acidic conditions. The HCO₃⁻ (10~50 mM) slightly inhibited, Cl⁻ (10~50 mM) gradually promoted, and HA (1~5 mg/L) significantly reduced NAP degradation by UV/chlorine process. The degradation intermediates and products were obtained via high-performance liquid chromatography with QE-MS/MS; NAP was degraded by demethylation, acetylation, and dicarboxylic acid pathways during the chlorination and UV/chlorination processes.

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