Paramagnetic aluminium β-diketiminate
2012
Moilanen, Jani | Borau-Garcia, Javier | Roesler, Roland | Tuononen, Heikki M.
The β-diketiminate ligand framework is shown to undergo reduction to form a neutral main group radical stabilized by spiroconjugation of the unpaired electron over the group 13 element centre. The synthesized paramagnetic complex was characterized by EPR spectroscopy and computational chemistry.
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