The palladium-catalyzed cyanation of indole C–H bonds with the combination of NH₄HCO₃ and DMSO as a safe cyanide source
2011
Ren, Xinyi | Chen, Jianbin | Chen, Fan | Cheng, Jiang
A palladium-catalyzed cyanation of the 3-position of indole sp² C–H bonds by the combination of NH₄HCO₃ and DMSO as the “CN” source was achieved to provide aromatic nitriles in moderate to good yields with excellent regioselectivity. It represents a practical and safe cyanation method.
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