Hierarchical multi-shell 66-nuclei silver nanoclusters trapping subvalent Ag₆ kernels
2019
Wang, Zhi | Yang, Feng-Lei | Yang, Yang | Liu, Qing-Yun | Sun, Di
Hierarchical nano structures are hard to fabircate. Here, we present three novel hierarchical multi-shell 66-nuclei silver nanoclusters, trapping ultrasmall Ag₆⁴⁺ nano-fragments by nine MoO₄²⁻ ions. This Ag₆@(MoO₄)₉ core is further wrapped by an outer Ag₆₀ shell. The Ag₆ kernel evolves from reduction involving DMF solvent. Carboxylate ligands are very important in the modulation of the polygon patterns on the Ag₆₀ shell.
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Эту запись предоставил National Agricultural Library