Variations in nitrate isotope composition of wastewater effluents by treatment type in Hong Kong

Archana, A.; Li, Luo; Shuh-Ji, Kao; Thibodeau, Benoit; Baker, David M.

Variations in nitrate isotope composition of wastewater effluents by treatment type in Hong Kong

2016

Archana, A. | Li, Luo | Shuh-Ji, Kao | Thibodeau, Benoit | Baker, David M.

Stable isotopes (δ15N, δ18O) can serve as tracers for sources of nitrogen in the receiving environment. Hong Kong discharges ~3×106m3d−1 of treated wastewater into the ocean from 68 facilities implementing preliminary to tertiary treatment. We sampled treated sewage from 18 plants across 5 treatment types and examined receiving seawater from northeast Hong Kong. We analyzed nitrate and nitrite (NO3−+NO2−, hereafter NOx) ammonium (NH4+), phosphate (PO4+) concentrations and δ15NNOx, δ18ONOx. Sewage effluents contained high mean nutrient concentrations (NO3−=260μmolL−1, NH4+=1400μmolL−1, PO4+=50μmolL−1) with some indication of nitrogen removal in advanced treatment types. Mean δ15NNOx of sewage effluents from all plants and treatment types (12‰) was higher than natural sources and varied spatially and seasonally. There was no overall effect of sewage treatment type on δ15NNOx. A mass balance model indicated that sewage (>68%) remains a dominant source of nitrate pollution in seawater in Tolo Harbor.

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