Copper-catalyzed hydroboration of propargyl-functionalized alkynes in water
2016
da Costa, Jessie S. | Braun, Roger K. | Horn, Pedro A. | Lüdtke, Diogo S. | Moro, Angélica V.
The Cu-catalyzed hydroboration of alkynes in operationally simple and environmentally friendly conditions is reported. The reactions are performed in water, at room temperature, under micellar catalysis. Conditions to form the α or β borylated products selectively have been found and as an application a protocol for the tandem hydroboration/Suzuki coupling in water was developed.
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