Ultra trace quantification of chromium(VI) in food and water samples by highly sensitive catalytic adsorptive stripping voltammetry with rubeanic acid

Abbasi, Shahryar; Bahiraei, Atousa

Ultra trace quantification of chromium(VI) in food and water samples by highly sensitive catalytic adsorptive stripping voltammetry with rubeanic acid

2012

Abbasi, Shahryar | Bahiraei, Atousa

A simple and highly selective and sensitive catalytic adsorptive stripping voltammetric procedure for determination of ultra trace levels of chromium(VI) on hanging mercury drop electrode is reported. The method is based on the adsorptive preconcentration of the Cr(III)–dithiooxamide (rubeanic acid) complex and the utilization of the catalytic reaction in the presence of nitrate. At optimized conditions the calibration graph is linear from 0.01 to 6ng/ml and detection limit is 0.002ng/ml for accumulation time of 50s. The interference of some common ions was studied and this method has been applied to the determination of chromium in food and waste water samples with satisfactory results.

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