Influence of Cd on atrazine degradation and the formation of three primary metabolites in water under the combined pollution

Xie, Dongyu; Chen, Chuansheng; Li, Cui; Wang, Qinghai

Influence of Cd on atrazine degradation and the formation of three primary metabolites in water under the combined pollution

2021

Xie, Dongyu | Chen, Chuansheng | Li, Cui | Wang, Qinghai

To understand the influence of Cd on atrazine (ATZ) degradation in aqueous solution, the degradation of different initial levels of ATZ (0.1, 0.5, 1.0, and 2.0 mg·L⁻¹) was investigated in the presence and absence of Cd²⁺ in a 20-day laboratory experiment. It was found that Cd²⁺ caused a significant decrease in ATZ degradation and increased its half-life from 17–34 days to 30–57 days (p < 0.0001). Regarding the three most common metabolites of ATZ, deethylatrazine (DEA) and deisopropylatrazine (DIA) were detected in water earlier than hydroxyatrazine (HYA). The DEA content was several times higher than the DIA and HYA contents, regardless of the presence or absence of Cd²⁺. In the presence of Cd²⁺, the DIA content was significantly lower and the HYA content was significantly higher. Furthermore, Cd²⁺ had a dose-dependent effect on HYA formation. Our results indicated that the coexistence of Cd²⁺ and ATZ resulted in greater herbicide persistence, thereby possibly increasing the risk of environmental contamination. DEA was still the predominant ATZ degradation product detected in water under the combined pollution, which was similar to the ATZ tendency.

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