Facile fabrication of mixed matrix membranes from simultaneously polymerized hyperbranched polymer/modified graphene oxide for MTBE/MeOH separation
2018
Wang, Lin | Wang, Naixin | Yang, Hengyu | An, Quanfu | Li, Bingbing | Ji, Shulan
The compatibility and dispensability of inorganic nanofillers within a polymer matrix is crucial for the separation performance of mixed matrix membranes. Using organic compounds to modify the surface of inorganic nanoparticles is commonly used to reduce the agglomeration of nanoparticles and to therefore improve the compatibility between the nanoparticles and the polymer matrix. In this study, graphene oxide (GO) nanosheets were modified by in-situ polymerized hyperbranched poly (methylene bisacryl amide amino ethyl piperazine) (HPMA) through electrostatic interactions. The modification of GO and polymerization of HPMA were simultaneously achieved. The HPMA-modified GO nanosheets were then used to fabricate separation membranes on ceramic tubular substrates via a vacuum-assisted assembly method. The chemical structure of HPMA molecules and the HPMA-modified GO nanosheets were confirmed by FT-IR, Raman, and 1H NMR spectroscopy. Raman mapping verified that the GO nanosheets were dispersed well in the polymer matrix. The HPMA-GO composite membranes thus prepared were used to separate methyl tert-butyl ether (MTBE)/methanol (MeOH) mixture by pervaporation. The optimized MeOH content in permeation and flux could reach 99.5 wt% and 0.41 kg m−2 h−1, respectively, when the feed MeOH content was 10 wt% at 40 °C. The composite membranes also showed a good stability in a 120-h running test. Therefore, the facile method presented in this study could provide a new avenue to fabricate mixed matrix membranes for pervaporation separation of MTBE/MeOH mixtures and other applications.
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Эту запись предоставил National Agricultural Library