Large Area Synthesis of a Nanoporous Two-Dimensional Polymer at the Air/Water Interface
2015
Murray, Daniel J. | Patterson, Dustin D. | Payamyar, Payam | Bhola, Radha | Song, Wentao | Lackinger, Markus | Schlüter, A.-Dieter | King, Benjamin T.
We present the synthesis of a two-dimensional polymer at the air/water interface and its nm-resolution imaging. Trigonal star, amphiphilic monomers bearing three anthraceno groups on a central triptycene core are confined at the air/water interface. Compression followed by photopolymerization on the interface provides the two-dimensional polymer. Analysis by scanning tunneling microscopy suggests that the polymer is periodic with ultrahigh pore density.
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