The origin of groundwater arsenic and fluorine in a volcanic sedimentary basin in central Mexico: a hydrochemistry hypothesis

Morales-Arredondo, Iván; Rodríguez, Ramiro; Armienta, Maria Aurora; Villanueva-Estrada, Ruth Esther

The origin of groundwater arsenic and fluorine in a volcanic sedimentary basin in central Mexico: a hydrochemistry hypothesis | L’ origine de l’arsenic et du fluor des eaux souterraines d’un bassin volcano-sédimentaire du Mexique Central: hypothèse hydrochimique El origen del arsénico y del flúor en el agua subterránea en una cuenca sedimentaria volcánica en México Central: una hipótesis hidroquímica 墨西哥中部火山沉积盆地地下水中砷和氟的起源:水文化学假设 A origem de arsênio e fluoreto no aquífero em uma bacia vulcânica sedimentar no México Central: uma hipótese hidrogeoquímica

2016

Morales-Arredondo, Iván | Rodríguez, Ramiro | Armienta, Maria Aurora | Villanueva-Estrada, Ruth Esther

A groundwater sampling campaign was carried out in the summer of 2013 in a low-temperature geothermal system located in Juventino Rosas (JR) municipality, Guanajuato State, Mexico. This groundwater presents high concentrations of As and F⁻ and high Rn counts, mainly in wells with relatively higher temperature. The chemistry of major elements was interpreted with different methods, like Piper and D’Amore diagrams. These diagrams allowed for classification of four groundwater types located in three hydrogeological environments. The aquifers are hosted mainly in alluvial-lacustrine sediments and volcanic rocks in interaction with fault and fracture systems. The subsidence, faults and fractures observed in the study area can act as preferential channels for recharge and also for the transport of deep fluids to the surface, especially in the basin plain. The formation of a piezometric dome and the observed hydrochemical behavior of groundwater suggest a possible origin of the As and F⁻. Geochemical processes occurring during water–rock interaction are related to high concentrations of As and F⁻. High temperatures and alteration processes (like rock weathering) induce dissolution of As and F⁻-bearing minerals, increasing the content of these elements in groundwater.

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