A Ru-catalyzed one-pot synthesis of homopropargylic amines from alkyl azides under photolytic conditions
2014
Jeong, Wook | Lee, Ji Hyung | Kim, Jungjoon | Lee, Won Jong | Seong, Ju-Hwa | Park, Jaiwook | Rhee, Young Ho
A new synthetic method for homopropargylic amines from alkyl azides is presented. A salient feature of this reaction is the involvement of N-unsubstituted imines as the key intermediates, which are generated from alkyl azides by Ru catalysis under photolytic conditions. Notably, this method avoids the use of a protective group strategy in the homopropargylic amine synthesis.
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