Template dissolution with NaOH–HCl in the synthesis of zeolite-templated carbons: Effects on oxygen functionalization and electrical energy storage characteristics
2019
Park, Hongjun | Terhorst, Steven K. | Bera, Raj Kumar | Ryoo, Ryong
Zeolite-templated synthesis is a versatile route to ordered microporous carbons built with single-walled sp² framework of various structures, but the use of hazardous HF to dissolve the zeolite template is still a critical safety issue. We investigated the template-removal process using NaOH and HCl, which are safer than HF. The results indicated that the residual ash content in the carbon could be lowered to less than 5 wt% when the template was removed by consecutive treatments using NaOH and HCl in a proper sequence depending on the zeolite framework type. The carbon obtained in this manner exhibited a rather increased supercapacitance in aqueous media at high current density, as compared to carbons from HF-washing. In the case of the non-aqueous supercapacitor, however, the washing with NaOH–HCl resulted in low capacitance. This was due to the effect of NaOH to generate oxygen-functional groups, which could lead to an increase in the hydrophilicity, and a decrease in the electrical conductivity. Furthermore, the oxygen-functional groups could serve as a base to graft organic amines. When the carbon was heated in H₂, the oxygen content decreased to a similar level to that of the HF-washed carbon, restoring the conductivity and electrochemical energy storage characteristics.
Показать больше [+] Меньше [-]Ключевые слова АГРОВОК
Библиографическая информация
Эту запись предоставил National Agricultural Library