Spatial Distribution of Available Trace Metals in Four Typical Mediterranean Soils: The Caia Irrigation Perimeter Case Study

There is a small sample of edaphic geochemistry studies over large geographic areas, especially studies that consider major reference soil groups (RSG) that evaluate both native concentrations of elements and anthropogenically contaminated soils in agricultural settings, considering the long-term effect of agricultural practices on landscape sustainability. In this study, four RSGs were analyzed for the available trace elements Ni, Cr, Cd, Pb, Cu, Mn, and Zn, including other edaphic properties from 2002 to 2012. The main objectives were to assess the range of concentrations of the selected elements in the four typical Mediterranean soils, Cambisols, Luvisols, Calcisols, and Fluvisols, with heavy anthropogenic input (HAI) and compare them to minimal anthropogenic input (MAI). For MAI, the background levels of Pb, Ni, Cd, and Cr were highest in Calcisols, differing from those of Cambisols, Luvisols, and Fluvisols (<i>p</i> < 0.01), Cu is highest both in Calcisols and Luvisols while Mn is higher in Cambisols and Fluvisols (<i>p</i> < 0.05). The background concentration of Zn was the same in all RSGs (<i>p</i> > 0.05). For HAI, the reference levels of Pb, Ni, Cd, Mn, and Cr were highest in the Calcisols, and Cu was high in all RSGs except Fluvisols, while Zn presented the lowest concentrations in the Luvisol RSG, with all these results considering a confidence interval of 95%. Predictive maps for the sampled elements, as well as the edaphic bioavailability, are provided. This environmental impact assessment suggests that the land use is departing from sustainable ecosystem service development and that territorial management practices, with conservation goals in mind, should be adopted.