Sulphate contamination, pH and conductivity of forest soils in two neighbouring mountains with different pollution in Slovakia from 1989 to 2013
Rastislav JANÍK | Eduard BUBLINEC | Martin KUBOV | Ján KUKLA | Branislav SCHIEBER
The Štiavnické vrchy Mts. were strongly affected by pollution mostly from an aluminium plant in 1953-1989. This paper compares contamination of soils between Štiavnické vrchy Mts. and the neighbouring little polluted Kremnické vrchy Mts. from results of a 25-year study. After a decrease of emissions in Slovakia at the beginning of the 1990s the sulphate sulphur content, acidity and conductivity of soil water have decreased only on the surface and at a depth of 0.10 m at the study site in the Štiavnické vrchy Mts. At the depth 0.25 m the increase of sulphurization (23.68 kg/ha S-SO42- per year) and acidity (pH 4.92) was observed. During the research, the total sulphate sulphur influx to this soil depth was 568.3 kg/ha. The average sulphur input in the study areas of the Kremnické vrchy Mts. decreased with depth: from 18.48 kg/ha/year in the surface humus to 6.85 kg/ha/year at a depth of 0.25 m. The maximum sulphur influx at the open plot was 24.06 kg/ha/year and in total 553.34 kg S-SO42-. A small increase of acidity at soil depths of 0.25 m at some sites was observed also in the Kremnické vrchy Mts. Regression analysis revealed a statistically significant influence of sulphate sulphur content in the atmospheric precipitation on the sulphur amount in the soil water. A significant correlation was also observed between the precipitation amount and the sulphur content in soil water. Data from monitoring revealed significant differences between the sulphur amounts at depths of 0.10 m and 0.25 m in these study areas.
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