Industrial parks emit large amounts of anthropogenic heat and aggravate the urban heat island effect, which has become a severe environmental problem worldwide. Few studies explored if the warming effect generated by concentrated industrial facilities (i.e., steel plants in this study) produces an intra-heat island effect in urban built-up areas. Sufficient evidence of an industrial heat island (IHI) effect is lacking, and new quantitative methods are urgently needed to address these issues. Therefore, we proposed a new scheme to quantify the warming effect of large, heat-emitting urban objects versus complex surroundings, and the IHI effect was accordingly defined at a finer scale. This study separated the industrial park from other artificial lands and comprehensively estimated the IHI effects' spatiotemporal variation. The IHI intensities were measured based on varied natural and urbanized references, which provided new evidence for the existence of the IHI effect over space and seasons. The land surface temperature (LST) profiles delineated the downward trend in LST variation from inside to surroundings in the IHI cases on both spatial and temporal scales. The time-series analysis revealed that the IHI effects demonstrated more significant disparities regarding the LSTs between the industrial parks and their surrounding backgrounds during warm seasons than in cold seasons. And a more severe IHI effect was observed in spring and summer, and the weakest IHI intensity occurred in winter. Moreover, the IHI intensity is positively associated to the anthropogenic heat, indicating that the industrial activities contribute to the increased LSTs of the industrial park to a great extent. The rationale of the IHI effect can broaden insight for understanding how urban industrial heat sources influence the regional thermal environment, especially at a finer scale.

Polybrominated diphenyl ethers (PBDEs) are aromatic compounds that containing bromine atoms, which possess high efficiency, good thermal stability. However, PBDEs had various known toxic effects and were characterized as persistent environmental pollutants. Exposure to a quinone-type metabolite of PBDEs (PBDEQ) is linked with excess production of intracellular reactive oxygen species (ROS) in our previous studies. Here, we observed that PBDEQ exposure led to ROS and mitochondrial dysfunction, which promoted canonical and non-canonical Nod-like receptor protein 3 (NLRP3) inflammasome activation. Further experiments demonstrated that PBDEQ exposure activated Toll-like receptors (TLRs), subsequently regulating nuclear factor kappa B (NF-κB) signaling. Moreover, lysosomal damage and K⁺ efflux were involved in PBDEQ-driven NLRP3 inflammasome activation. Our in vivo study also illustrated that PBDEQ administration induced liver inflammation in male C57BL/6J mice. Cumulatively, our current finding provided novel insights into PBDEQ-induced pro-inflammatory responses.

Raw biochar with high pH possibly stimulated ammonia (NH₃) volatilization in the agricultural soil. We hypothesized that the modified biochar (MBC) with low pH can synchronically decrease the NH₃ and nitrous oxide (N₂O) losses. We performed a two-year experiment to clarify how citric acid MBC influence the NH₃ volatilization and N₂O emission as well as the underlying mechanisms. Two typical paddy soils, i.e., Hydragric Anthrosol and Haplic Acrisol, receiving equal urea N with 240 kg ha⁻¹ but varied rates of MBC with 0, 5, 10, and 20 t ha⁻¹ (named Urea, Urea + MBC5, Urea + MBC10, and Urea + MBC20, respectively) were studied. The results showed that MBC-amended treatments effectively mitigated the NH₃ volatilization from Hydragric Anthrosol and Haplic Acrisol by 29.6%–57.9% and 30.5%–62.4% in 2017, and by 16.5%–21.0% and 24.5%–35.0% in 2018, respectively, compared to Urea treatment. In addition, significantly lower N₂O emissions with averaged 38.3% and 43.1% in 2017, and 51.7% and 26.7% were recorded under Hydragric Anthrosol and Haplic Acrisol, respectively, following the MBC application (P < 0.05). Increased MBC addition performed higher efficacy on mitigating NH₃ volatilization, particularly in the first rice season, while this “dosage effect” was not found for N₂O reduction. Lowered pH in overlying water, enhanced adsorption of NH₄⁺-N and its nitrification rate likely contributed to the lower NH₃ volatilization as result of MBC addition. The nirS and nosZ gene copies were not changed by MBC, while the nirK gene copies were decreased as result of MBC amendment by 8.3%–25.2% under Hydragric Anthrosol and by 21.8%–24.9% under Haplic Acrisol. Consequent lower ratio of nirK/(nirS + nosZ) explained the mitigation effect of MBC on N₂O emission. In conclusion, the present two-year study recommends that MBC applied at a low dosage can perform positive effect on controlling the nitrogenous gas pollutants from paddy soil.

Chemical sensors that can detect volatile organic compounds (VOCs) are the subject of extensive research efforts. Among various sensing technologies, molecularly imprinted polymers (MIPs) are regarded as a highly promising option for their detection with many advantageous properties, e.g., specific binding-site for template molecules, high recognition specificity, ease of preparation, and chemical stability. This review covers recent advances in the sensing application of MIPs toward various types of VOCs (e.g., aliphatic and aromatic compounds). Particular emphasis has been placed on multiple approaches to the synthesis of MIP-based VOC sensors in association with their performance and sensing mechanisms. Current challenges and opportunities for new VOC-sensing applications are also discussed based on MIP technology.

Air pollution exposure during early-life is associated with altered brain development, but the precise periods of susceptibility are unknown. We aimed to investigate whether there are periods of susceptibility of air pollution between conception and preadolescence in relation to white matter microstructure and brain volumes at 9–12 years old. We used data of 3515 children from the Generation R Study, a population-based birth cohort from Rotterdam, the Netherlands (2002–2006). We estimated daily levels of nitrogen dioxide (NO2), and particulate matter (PM2.5 and PM2.5absorbance) at participants’ homes during pregnancy and childhood using land-use regression models. Diffusion tensor and structural brain images were obtained when children were 9–12 years of age, and we calculated fractional anisotropy and mean diffusivity, and several brain structure volumes. We performed distributed lag non-linear modeling adjusting for socioeconomic and lifestyle characteristics. We observed specific periods of susceptibility to all air pollutants from conception to age 5 years in association with lower fractional anisotropy and higher mean diffusivity that survived correction for multiple testing (e.g., −0.85 fractional anisotropy (95%CI -1.43; −0.27) per 5 μg/m³ increase in PM2.5 between conception and 4 years of age). We also observed certain periods of susceptibility to some air pollutants in relation to global brain and some subcortical brain volumes, but only the association between PM2.5 and putamen survived correction for multiple testing (172 mm³ (95%CI 57; 286) per 5 μg/m³ increase in PM2.5 between 4 months and 1.8 year of age). This study suggested that conception, pregnancy, infancy, toddlerhood, and early childhood seem to be susceptible periods to air pollution exposure for the development of white matter microstructure and the putamen volume. Longitudinal studies with repeated brain outcome measurements are needed for understanding the trajectories and the long-term effects of exposure to air pollution.

Hydrogen sulfide (H₂S) is a flammable, corrosive and lethal gas even at low concentrations (ppm levels). Hence, the capture and removal of H₂S from various emitting sources (such as oil and gas processing facilities, natural emissions, sewage treatment plants, landfills and other industrial plants) is necessary to prevent and mitigate its adverse effects on human (causing respiratory failure and asphyxiation), environment (creating highly flammable and explosive environment), and facilities (resulting in corrosion of industrial equipment and pipelines). In this review, the state-of-the-art technologies for H₂S capture and removal are reviewed and discussed. In particular, the recent technologies for H₂S removal such as membrane, adsorption, absorption and membrane contactor are extensively reviewed. To date, adsorption using metal oxide-based sorbents is by far the most established technology in commercial scale for the fine removal of H₂S, while solvent absorption is also industrially matured for bulk removal of CO₂ and H₂S simultaneously. In addition, the strengths, limitations, technological gaps and way forward for each technology are also outlined. Furthermore, the comparison of established carbon capture technologies in simultaneous and selective removal of H₂S–CO₂ is also comprehensively discussed and presented. It was found that the existing carbon capture technologies are not adequate for the selective removal of H₂S from CO₂ due to their similar characteristics, and thus extensive research is still needed in this area.

The presence of large amounts of antibiotic resistance genes (ARGs) in livestock manures poses an impending, tough safety risk to ecosystems. To investigate more comprehensively the mechanisms of ARGs removal from industrial-scale composting of livestock manure based on biochar addition, we tracked the dynamics of bacterial community and ARGs at various stages of aerobic composting of livestock manures with 10% biochar. There were no significant effects of biochar on the bacterial community and the profiles of ARGs. During aerobic composting, the relative abundance of ARGs and mobile genetic elements (MGEs) showed overall trends of decreasing and then increasing. The key factor driving the dynamics of ARGs was bacterial community composition, and the potential hosts of ARGs were Caldicoprobacter, Tepidimicrobium, Ignatzschineria, Pseudogracilibacillus, Actinomadura, Flavobacterium and Planifilum. The retention of the thermophilic bacteria and the repopulation of the initial bacteria were the dominant reasons for the increase in ARGs at maturation stage. Additionally, among the MGEs, the relative abundance of transposon gene was substantially removed, while the integron genes remained at high relative abundance. Our results highlighted that the suitability of biochar addition to industrial-scale aerobic composting needs to be further explored and that effective measures are needed to prevent the increase of ARGs content on maturation stage.

Natural processes and human activities play a crucial role in changing the nitrogen cycle and increasing nitrous oxide (N₂O) emissions, which are accelerating at an unprecedented rate. N₂O has serious global warming potential (GWP), about 310 times higher than that of carbon dioxide. The food production, transportation, and energy required to sustain a world population of seven billion have required dramatic increases in the consumption of synthetic nitrogen (N) fertilizers and fossil fuels, leading to increased N₂O in air and water. These changes have radically disturbed the nitrogen cycle and reactive nitrogen species, such as nitrous oxide (N₂O), and have impacted the climatic system. Yet, systematic and comprehensive studies on various underlying processes and parameters in the altered nitrogen cycle, and their implications for the climatic system are still lacking. This paper reviews how the nitrogen cycle has been disturbed and altered by anthropogenic activities, with a central focus on potential pathways of N₂O generation. The authors also estimate the N₂O–N emission mainly due to anthropogenic activities will be around 8.316 Tg N₂O–N yr⁻¹ in 2050. In order to minimize and tackle the N₂O emissions and its consequences on the global ecosystem and climate change, holistic mitigation strategies and diverse adaptations, policy reforms, and public awareness are suggested as vital considerations. This study concludes that rapidly increasing anthropogenic perturbations, the identification of new microbial communities, and their role in mediating biogeochemical processes now shape the modern nitrogen cycle.

The rapid growth of plastic wastes exceeds efforts to eliminate plastic pollution owing to the outbreak of COVID-19 in 2020 and then aggravates inherent environmental threats to the ecosystem. The paper provided a short introduction relating to the hazards of plastic wastes on environment and a detailed statement about plastic toxicity on human. The article stated on plastic how to enter the body and cause harm for us step by step. Given the toxicity and harm of plastic wastes on human, the degradation of plastic wastes via the physical, chemical and biotic methodologies is looked back. The advanced physical techniques are introduced briefly at firstly. Additionally, evaluate on chemical method for plastic decomposition and review on biotic degradation of plastic. The reactive oxygen species and the enzymes play a crucial role in chemical and biotic degradation processes, respectively. The reactive oxygen species are derived from the activated state of oxides, and the enzymes that aid the microorganism to ingest plastic through its metabolic mechanism are secreted by the microorganism. Subsequently, the potential possibility of upcycling plastic is analyzed from two aspects of the technology and application. The innovative technology utilizes sunlight as driver-power of plastic upcycling. And the carbon capture, utilization and sequestration and the growth substrate provided the novel guided directions for plastic recycle. Lastly, the three suggestions on plastic waste management are expected to establish an economy and efficient plastic sorting system, and two engineering solutions on plastic recycle are to make a contribution for sustainable upcycling of plastic.

In 2018, over 30,000 L of fluorine-free firefighting foam was used to extinguish an industrial warehouse fire of uncharacterized chemical and industrial waste. Contaminated firewater and runoff were discharged to an adjacent freshwater creek in Melbourne, Australia. In this study, we applied nontarget analysis using liquid chromatography quadrupole time-of-flight mass spectrometry (LC-QToF-MS) to 15 surface water samples to investigate the presence of legacy, novel and emerging per-and polyfluoroalkyl substances (PFAS). We identified six novel and emerging fluorotelomer-based fluorosurfactants in the Australian environment for the first time, including: fluorotelomer sulfonamido betaines (FTABs or FTSA-PrB), fluorotelomer thioether amido sulfonic acids (FTSASs), and fluorotelomer sulfonyl amido sulfonic acids (FTSAS-So). Legacy PFAS including C₆–C₈ perfluoroalkyl sulfonic acids, C₄–C₁₀ perfluoroalkyl carboxylic acids, and perfluoro-4-ethylcyclohexanesulfonate were also detected in surface water. Of note, we report the first environmental detection of ethyl 2-ethenyl-2-fluoro-1-(trifluoromethyl) cyclopropane-1-carboxylate. Analysis of several Class B certified fluorine-free foam formulations allowed for use in Australia revealed that there was no detectable PFAS. Patterns in the homologue profiles of fluorotelomers detected in surface water are consistent with environments impacted by fluorinated aqueous film-forming foams. These results provide strong evidence that firewater runoff of stockpiled fluorinated firefighting foam was the dominant source of detectable PFAS to the surrounding environment.