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Pre- and post-industrial levels of polycyclic aromatic hydrocarbons in sediments from the Estuary and Gulf of St. Lawrence (eastern Canada) Полный текст
2022
Corminboeuf, Anne | Montero-Serrano, Jean-Carlos | St-Louis, Richard | Dalpé, Allyson | Gélinas, Yves
The concentrations of 23 polycyclic aromatic hydrocarbons (PAHs; 16 parent PAHs and 7 alkyl-PAHs) were determined in 45 surface sediment and 7 basal sediment box core samples retrieved from the Estuary and Gulf of St. Lawrence in eastern Canada. The concentration sums of 16 priority PAHs (Σ₁₆PAHs) in the surface sediments (representing modern times or at least younger than the last decade) ranged from 71 to 5672 ng g⁻¹. Σ₁₆PAHs in the basal sediments ranged from 93 to 172 ng g⁻¹ among the pre-industrial samples (pre-1900 common era or CE) and from 1216 to 1621 ng g⁻¹ among the early post-industrial samples (~1930s and ~1940s CE). The highest Σ₁₆PAH values occurred in samples retrieved from the Baie-Comeau-Matane area, an area affected by intense industrial anthropogenic activities. Source-diagnostic PAH ratios suggest a predominance of pyrogenic sources via atmospheric deposition, with a minor contribution of petrogenic seabed pockmark sources. The PAH concentrations in the sediments from the study areas reveal low ecological risks to benthic or other organisms living near the water-sediment interface.
Показать больше [+] Меньше [-]Assessment of chloride natural background levels by applying statistical approaches. Analyses of European coastal aquifers in different environments Полный текст
2022
Pulido-Velazquez, D. | Baena-Ruiz, L. | Fernandes, J. | Arnó, G. | Hinsby, K. | Voutchkova, D.D. | Hansen, B. | Retike, I. | Bikše, J. | Collados-Lara, A.J. | Camps, V. | Morel, I. | Grima-Olmedo, J. | Luque-Espinar, J.A.
Assessment of chloride natural background levels by applying statistical approaches. Analyses of European coastal aquifers in different environments Полный текст
2022
Pulido-Velazquez, D. | Baena-Ruiz, L. | Fernandes, J. | Arnó, G. | Hinsby, K. | Voutchkova, D.D. | Hansen, B. | Retike, I. | Bikše, J. | Collados-Lara, A.J. | Camps, V. | Morel, I. | Grima-Olmedo, J. | Luque-Espinar, J.A.
Estimated natural background levels (NBLs) are needed to assess groundwater chemical status according to the EU Groundwater Directive. They are commonly derived for different substances by applying statistical methodologies. Due to the complexity of the sea water intrusion process, some of those methods do not always provide appropriate assessment of chloride NBLs. This paper analyzes the applicability of different NBL estimation methods in five EU coastal aquifers with significant differences in available datasets and hydrogeological settings. A sensitivity analysis of results to different constraints was performed to remove samples with anthropogenic impacts. A novel statistical approach combining different methods to identify the range of chloride NBLs is proposed. In all pilots the estimated NBLs were below 85 mg/L and fitted well with previous studies and expert judgment, except Campina del Faro aquifer (the maximum being 167.5 mg/L). Although this approach is more time consuming, it provides a more robust solution.
Показать больше [+] Меньше [-]Assessment of chloride natural background levels by applying statistical approaches. Analyses of European coastal aquifers in different environments Полный текст
2022
Pulido-Velazquez, David | Baena-Ruiz, Leticia | Fernandes, J. | Arnó, G. | Hinsby, Klaus | Voutchkova, Denitza | Hansen, B. | Retike, Inga | Bikše, Jānis | Collados-Lara, Antonio-Juan | Camps, V. | Morell, Ignacio | Grima-Olmedo, Juan | Luque-Espinar, J. A.
Estimated natural background levels (NBLs) are needed to assess groundwater chemical status according to the EU Groundwater Directive. They are commonly derived for different substances by applying statistical methodologies. Due to the complexity of the sea water intrusion process, some of those methods do not always provide appropriate assessment of chloride NBLs. This paper analyzes the applicability of different NBL estimation methods in five EU coastal aquifers with significant differences in available datasets and hydrogeological settings. A sensitivity analysis of results to different constraints was performed to remove samples with anthropogenic impacts. A novel statistical approach combining different methods to identify the range of chloride NBLs is proposed. In all pilots the estimated NBLs were below 85 mg/L and fitted well with previous studies and expert judgment, except Campina del Faro aquifer (the maximum being 167.5 mg/L). Although this approach is more time consuming, it provides a more robust solution.
Показать больше [+] Меньше [-]Impact of plastic bags on the benthic system of a tropical estuary: An experimental study Полный текст
2022
Clemente, Caroline C.C. | Paresque, Karla | Santos, Paulo J.P.
Plastic bags are among the most discarded waste items as they are generally only used once and are often improperly eliminated and transported by rivers and estuaries to the ocean. We developed an experimental design to mimic the effect of plastic bag deposition in a tropical estuary and investigated its short-term impact on benthic community structure. We observed a significant influence of the presence of plastic bags on the abundance, richness and diversity of benthic fauna after an eight-week exposure period. Plastic bags acted as a barrier and interfered in processes that occur at the water-sediment interface, such as organic matter and silt-clay deposition. Our results indicate that plastic bags, in addition to directly affecting benthic fauna, may alter processes such as carbon burying, known as “blue carbon”, thus making its storage in the sediment more difficult.
Показать больше [+] Меньше [-]Anchored bulk carriers have substantial impacts on the underwater soundscape in Cowichan Bay, British Columbia Полный текст
2022
Murchy, Kelsie A. | Vagle, Svein | Juanes, Francis
In recent decades shipping traffic has increased, leading to elevated underwater ambient noise levels. Research has been conducted on the noise generated by ships underway, however little is known about potential noise from ships at anchor. In coastal regions, commercial vessels can seek anchorages prior to entering port, leading to concern regarding the impacts on the soundscape and marine ecosystems. Cowichan Bay, British Columbia, a coastal region (800 Ha) 70 km away from the Port of Vancouver, was examined as a case study to understand the possible soundscape contribution from anchored bulk carriers. When a carrier anchored, sound pressure levels (SPL: 20–24,000 Hz) were elevated 2–8 dB re: 1 μPa throughout the bay. These results demonstrate the change anchored carriers can have on underwater soundscapes and is an important step in understanding the potential impact these vessels may have on marine organisms and important ecosystems.
Показать больше [+] Меньше [-]Quantitative assessment of microplastic in sandy beaches of Gujarat state, India Полный текст
2022
Rabari, Vasantkumar | Patel, Krupal | Patel, Heris | Trivedi, Jigneshkumar
The present study was carried out to quantify microplastic prevalence among 20 sandy beaches on the Gujarat coast. Beaches were categorised into three different classes, viz. low-impacted sites, moderately impacted sites, and highly impacted sites based on anthropogenic pressure. Microplastic (MP) (≤ 5 mm) contamination on the beaches varied with an average of 1.4 MPs/kg to 26 MPs/kg sediment. Sutrapada site-1 and Porbandar showed the highest and lowest mean abundance of microplastics, respectively, among 20 selected beaches. Out of the total assessed microplastics, threads were the maximum (89.98%), followed by the films (4.75%), fragments (3.36%) and foam (1.89%). In terms of colour and size, different microplastics were recorded in this study. The chemical composition of microplastics was identified by ATR-FTIR as polypropylene (47.5%), polyethylene (26%), and polystyrene (25%). Tourism and fishing activities are the possible sources of higher microplastic contamination at highly impacted sites.
Показать больше [+] Меньше [-]Metals and metalloids in Antarctic krill and water in deep Weddell Sea areas Полный текст
2022
Mirzoeva, Natalia | Tereshchenko, Nataliya | Paraskiv, Artem | Proskurnin, Vladislav | Stetsiuk, Aleksandra | Korotkov, Andrey
The study on the concentration of trace elements in Antarctic krill and in water in the deep areas of the Atlantic sector of the Antarctic was performed. Concentrations of 22 trace elements were studied to determine their spatial distribution in krill, and to assess the accumulation ability of the krill against 8 of them. The trace elements concentration in krill diminished in the following order: Fe > Cu > Zn > Bа > B > Se > As > Cr > Ni > Ag > Li > Mn > V > Mo > Cd > Co > Hg > Be. Concentrations of Pb, Ti, Tl, Sb were below their detection limits. Concentration factors of trace elements by krill varied from n × 10² to n × 10⁴. The Cu and As concentrations in dry krill exceeded their MPC. Concentrations of all trace elements in wet mass of krill were not exceeded established regulative values.
Показать больше [+] Меньше [-]Lipid profiling differentiates the effect of ambient microenriched copper on a coral as an advanced tool for biomonitoring Полный текст
2022
Tang, Chuan-Ho | Shi, Shu-Han | Lin, Jingyu | Wang, Wei-Hsien
Copper can be beneficial or harmful to coral at environmentally relevant levels, making environmental monitoring a challenging. Membrane lipids make the cell a dynamic environment according to the circumstances; thus, the lipid profile should be indicative of an environmental/physiological state. To gain more insight into the copper effect on coral health and be a basis of biomonitoring, glycerophosphocholine profiling of coral exposed to microenriched copper levels was conducted in this study. The copper microenrichments resulted in a diacritical effect of decreasing carbonic anhydrase activity, following a supplementation effect, on coral lipid metabolism. Microdifferences in copper levels are critical to determine the coral metabolic state and were therefore included in this study. In addition, an excellent quantitative model correlating the coral lipid variation with the exposed copper levels or the induced physiological effect was obtained to demonstrate its performance for biomonitoring.
Показать больше [+] Меньше [-]Assessment of trace metal concentrations in Indian Ocean silky sharks Carcharhinus falciformis and their toxicological concerns Полный текст
2022
Wang, Ming-Huang | Chen, Chiu-Wen | Chen, Chih-Feng | Tsai, Wen-Pei | Dong, Cheng-Di
This study assessed the concentrations of nine trace metals from juvenile C. falciformis caught from Indian Ocean. This study also discussed the metal pollution index (MPI) and bioconcentration factor (BCF) of each element, and their correlations. Further, the potential health risks of consuming shark muscles (THI) were evaluated. Results showed the mean concentrations of 9 elements as follows: Cu (0.36 ± 0.17), Zn (5.19 ± 16.6), Pb (0.12 ± 0.23), Cd (0.17 ± 0.21), Cr (0.57 ± 1.61), Ni (0.086 ± 0.51), As (1.36 ± 0.83), Co (0.000073 ± 0.0074), and V (0.0024 ± 0.0094) mg/kg ww. The BCF values of the elements were higher than 1, with Co and V being the lowest indicating their bioaccumulative behavior. Correlation analysis showed MPI to be highly correlated with Cu, indicating its greater contributions to the total pollution load. Principal components analysis explained 81.0% of the variability in biometric characteristics and metal concentrations. Health risk assessment for consuming shark muscle in Taiwanese male and female adults suggests potential chronic non-carcinogenic health hazards.
Показать больше [+] Меньше [-]Two decades of seawater acidification experiments on tropical scleractinian corals: Overview, meta-analysis and perspectives Полный текст
2022
Godefroid, Mathilde | duPont, Sam | Metian, Marc | Hédouin, Laetitia
Ocean acidification has emerged as a major concern in the last fifteen years and studies on the impacts of seawater acidification on marine organisms have multiplied accordingly. This review aimed at synthesizing the literature on the effects of seawater acidification on tropical scleractinians under laboratory-controlled conditions. We identified 141 articles (published between 1999 and 2021) and separated endpoints into 22 biological categories to identify global trends for mitigation and gaps in knowledge and research priorities for future investigators. The relative number of affected endpoints increased with pH intensity (particularly for endpoints associated to calcification and reproduction). When exposed to pH 7.6–7.8 (compared to higher pH), 49% of endpoints were affected. The diversity in experimental designs prevented deciphering the modulating role of coral life stages, genera or duration of exposure. Finally, important bias in research efforts included most experiments on adult corals (68.5%), in 27 out of 150 (18%) coral ecoregions and exclusively from shallow-waters.
Показать больше [+] Меньше [-]Pixel-level image classification for detecting beach litter using a deep learning approach Полный текст
2022
Hidaka, Mitsuko | Matsuoka, Daisuke | Sugiyama, Daisuke | Murakami, Koshiro | Kako, Shin'ichiro
Mitigating and preventing beach litter from entering the ocean is urgently required. Monitoring beach litter solely through human effort is cumbersome, with respect to both time and cost. To address this problem, an artificial intelligence technique that can automatically identify different-sized beach litter is proposed. The technique was established by training a deep learning model that enables pixel-wise classification (semantic segmentation) using beach images taken by an observer on the beach. Eight segmentation classes that include two beach litter classes were defined, and the results were qualitatively and quantitatively verified. Segmentation performance was adequately high based on three metrics: Intersection over Union (IoU), precision, and recall, although there is room for further improvement. The potency of the method was demonstrated when it was applied to images taken in different places from training data images, and the coverage of artificial litter calculated and discussed using drone images provided ground truth.
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