Free-living nematodes were investigated in three Mediterranean commercial ports (Ancona and Trieste, Italy; Koper, Slovenia) in terms of abundance, diversity and functionality. Results indicated that r-strategist genera were dominant in all ports and that a more diverse assemblage characterized Trieste, despite the high contamination levels, suggesting a potential adaptation to long-standing contamination. The main environmental factor that shaped the assemblage in all ports were Total Polycyclic Aromatic Hydrocarbons, while Total Organic Carbon and the grain-size were less relevant. A co-occurrence analysis was applied for identifying which genera cohesively respond to site-specific environmental conditions in order to recalibrate and implement the sets of bioindicator genera in relation to their different opportunistic behaviour. Finally, we provided some suggestions for a proper application of the nematode indices (Maturity Index, Index of Trophic Diversity, Shannon diversity) in order to encourage the use of free-living nematodes for the environmental quality assessment of commercial ports.

Rivers are the key conduits for land-to-sea debris transport. We present in situ monitoring data of macro debris and microplastic along the supercritical Citarum River in Indonesia We identified the dams as concentrated areas of microplastic. Plastics accounted for 85% of the riverine debris (5369 ± 2320 items or 0.92 ± 0.40 tons daily). We estimated macrodebris releases of 6043 ± 567 items or 1.01 ± 0.19 tons daily with a microplastic concentration of 3.35 ± 0.54 particles per m³ from Citarum River to sea. It has been suggested that population density and urbanization rate are major factors determining the spatiotemporal variability of macrodebris and microplastic abundances in the Citarum River. Our research highlights the importance of long-term monitoring to estimate debris and microplastics inflows along the Indonesian river to the world ocean as a benchmark for the reduction of macro and microdebris into the environment.

Distribution of five heavy metals (Cd, Cr, Cu, Pb, and Zn) in molluscan and echinoderm species collected from Kerala and Gulf of Mannar in Southern India is presented. Atomic absorption spectrometry was used to determine metal concentrations. Concentrations of metals showed a descending order of Zn > Cu > Pb > Cd > Cr. Zn and Cu might have originated from both natural and man-made sources. However, Cd, Cr, and Pb could have strong anthropogenic influences such as harbour activities and untreated industrial and agricultural runoff. Bioaccumulation factor (BAF) value of Cd in two edible bivalves from Munambam is slightly greater than one. Regular consumption of Cd-loaded shellfish can cause serious health hazards and concerns to humans. BAF results showed that Zn, Cu, Pb, and Cd were more bioaccumulated and beyond the threshold limits in certain species. It is evident that consumption of shellfish from the Kerala coastal waters may have adverse health impacts to the consumers.

Maritime traffic is increasing globally, with a four-fold increase in commercial vessel movements between 1992 and 2012. Vessels contribute to noise and air pollution, provide pathways for non-native species, and collide with marine wildlife. While knowledge of shipping trends and potential environmental impacts exists at both local and global levels, key information on vessel density for regional-scale management is lacking. This study presents the first in-depth spatio-temporal analysis of shipping in the north-east Atlantic region, over three years in a five-year period. Densities increased by 34%, including in 73% of Marine Protected Areas. Western Scotland and the Bay of Biscay experienced the largest increases in vessel density, predominantly from small and slow vessels. Given well-documented impacts that shipping can have on the marine environment, it is crucial that this situation continues to be monitored – particularly in areas designated to protect vulnerable species and ecosystems which may already be under pressure.

The history of metal pollution in the semi-enclosed and human-influenced marine system of the Boka Kotorska Bay (Southern Adriatic) was studied considering geological composition of the surrounding catchment, the sedimentation rate and the mineralogical and early diagenetic processes in the recent sediments. The determination of background concentrations of metals, undertaken for the first time in this environment, proved to be particularly important for Ni and Cr, which are naturally enriched in the sediments of the southern Adriatic. The results showed widespread moderate contamination with Pb and Sn since the 1970s, while the upper layers of sediments near shipyards, marinas and urban areas were more contaminated with Sn, Cu, Pb, Zn, Cd, As, Sb and Mo. The transport of material through the narrow straits separating different parts of Boka Kotorska Bay resulted in a different geochemical composition of the smaller bays and a limited distribution of contaminated sediments from local sources.

This paper presents a tightly coupled experimental and kinetic approach for efficient remediation of oil spill from contaminated marine intertidal zone surface through a methodical strategy that deals with biosurfactant mediated washing strategy. The study deals with production, optimization and characterization of lipopeptide biosurfactant from Bacillus subtilis T1 and its application in remediation of oil contaminants from mimic model system of various marine intertidal zone i.e. woodland-Group1, saltmarsh-Group2, mangrove-Group3 and mudflats-Group4. Results demonstrates enhanced washing performance with oil desorption rate of 35 % in Group 4, 17.22 %, 15.6 % and 11 % in Group 3, 2 and 1 along with bio surfactant recovery rate of 41 %, 48.7 %, 51.71 % and 50.3 % respectively. Further, the washing strategy was efficient in soil detoxification with highest rate in Group 4. The kinetic validation depicts good match among experimental data and Lagergren pseudo second order data.

Particulate matter (PM₂.₅) generated in large cities creates new problems in marine ecosystems and may adversely affect its inhabitants. However, the mechanisms underlying the same remain unclear; hence, we investigated the effects of PM₂.₅ on life history traits (e.g., mortality, development, and fecundity), cellular reactive oxygen species (ROS) levels, antioxidant enzyme (e.g., glutathione peroxidase [GPx], superoxide dismutase [SOD], and catalase [CAT]) activities, and the transcript levels of detoxification-related genes (cytochrome P450s [CYPs]) and antioxidant (glutathione S-transferases [GSTs]) in the copepod Tigriopus japonicus. Among the life history traits, developmental time was the only trait to significantly deviate (P < 0.05) in response to PM₂.₅ (compared to that in the controls). Significant changes in ROS levels and antioxidant enzymatic activities (P < 0.05) in response to PM₂.₅, suggested that PM₂.₅ can induce oxidative stress, leading to adverse effects on the T. japonicus life history. In addition, PM₂.₅ induced a differential regulation of various CYP and GST genes, particularly CYP307E1, GST-kappa, and GST-sigma were significantly upregulated (P < 0.05), suggesting that these genes likely play crucial roles in detoxification mechanisms and could be useful as reliable biomarkers for PM₂.₅ toxicity. Overall, the results of this study provide new insights into the potential toxicity of PM₂.₅.

In recent decades the development of desalination plants (DPs) for desalination of seawater has increased dramatically, while little attention has been paid to the effects of this activity on the accumulation of heavy metals (HMs) in the sediments of affected ecosystems. The present study was implemented to evaluate (1) heavy metal accumulation in sediments impacted by DPs discharges, (2) spatial and temporal changes of HMs and the contamination degree by different types of pollution indexes (single and integrated indices), and (3) ecological risk assessment of cadmium (Cd), lead (Pb), zinc (Zn) and copper (Cu) in sediments affected by DPs discharges. A total of 288 sediment samples were collected seasonally at 24 stations from November 2019 to October 2020. Analysis of HMs concentrations in sediments near the desalination plant discharge provided evidence of local contamination. Maximum concentration of Cu and Pb elements were found in sediments near the desalination plant discharge point. Hierarchical cluster analysis revealed clear segregation of stations impacted by desalination plant discharges and away from discharges. The values of PLI index in sediments of all sampling stations were < 1, indicating that there was no metal pollution by this index. The potential ecological risk index (PERI) ranged from 5.33 ± 0.51 to 11.81 ± 4.98 in sampling sediments and were classified as “low potential ecological risk”. These results demonstrate that the DPs discharge increased HMs concentrations in the sediments in close proximity to outlets. The necessary and practical regulations and policies regarding the rejection of the DPs discharge and disposal of chemical compounds must be implemented and enforced.

The rapid growth in the global production of organophosphate esters (OPEs) has resulted in their high environmental concentrations. The low removal rate of OPEs makes the effluents of wastewater treatment plants be one of the major sources of OPEs. Due to relatively high solubility and mobility, OPEs can be carried to the coastal environment through river discharge and atmospheric deposition. Therefore, the coastal environment can be an important OPE sink. Previous studies have shown that OPEs were widely detected in coastal atmospheres, water, sediments, and even aquatic organisms. OPEs can undergo various environmental processes in the coastal environment, including adsorption/desorption, air–water exchange, and degradation. In addition, bioaccumulation of OPEs was observed in coastal biota but current concentrations would not cause significant ecological risks. More efforts are required to understand the environmental behaviors of OPEs and address resultant environmental and health risks, especially in the complicated environment.

Historical ⁹⁰Sr activity in seawater was established in the China seas from 1963 to 2018. Based on the exponential decrease in ⁹⁰Sr activity in seawater, the effective half-life (EHL) of ⁹⁰Sr was quantified to be 11.5 ± 1.6 a, 16.5 ± 2.4 a, 27.2 ± 6.2 a, and 26.7 ± 4.3 a in the Bohai Sea, Yellow Sea, East China Sea, and South China Sea, respectively. We found contrasting patterns in the EHL of ⁹⁰Sr and ¹³⁷Cs in the marginal seas and open oceans that were closely related to the subtly different pathways of ⁹⁰Sr and ¹³⁷Cs in marine environment. Additionally, we demonstrated that Fukushima-derived ⁹⁰Sr (<0.01 Bq/m³) would be difficult to identify in the China seas. Our study not only provided the key parameter of the EHL in marine models for predicting the ⁹⁰Sr activity in the China seas in the post-Fukushima era but also enhanced our understanding of ⁹⁰Sr behavior and its fate in marine environments.