The water volume for sediment transport affects the distribution of sediments in rivers and offers important guidance for river dredging, management and remediation. In this paper, with daily water and sediment data of major hydrological stations of main stream of Liaohe River from 1988 to 2010, we calculated the average water volume and unit water volume for sediment transport of the year with the methods of sediment discharge, sediment concentration and erosion and silting ratio correction that are based on net water volume method. We analyzed the relations between change process of water volume for sediment transport and its impact factors to identify the critical water volume for sediment transport for non-scouring and non-silting situation. The results showed that (1) according to the calculation with the hydrological data from the major hydrological stations in Tongjiangkou, Tieling, Mahushan, Ping’anpu and Liujianfang, the average water volume and the unit water volume for sediment transport during the flood season of the year were 13.88×108m3 and 1136.62m3/t respectively; (2) According to the theoretical calculation, the water demand model for hydraulic sediment dredging in the major reaches of the main stream of Liaohe River was determined and there was linear function relationship between the sediment discharge and the water demand. When the channel kept the sediment from silting, the water demand at Tieling was ≥18.73×108m3, ≥5.49×108m3 at Mahushan, ≥2.90×108m3 at Ping’anpu and ≥10.97×108m3 at Liaozhong. In a word, net water volume method can accurately calculate the amount of sediment transport in sediment-laden rivers with a prospect of broad application.

The modelling of chlorophyll-a concentration helps to restrict the harmful effects in marine species caused by increased nutrient loads. The derived satellite data are often used for the monitoring of marine ecology. The common usage of satellite data is monthly average data to avoid the problem of missing values. In order to reduce the effect of missing data, this study employed the cubic spline model by using a satellite data for investigating seasonal variations of chlorophyll-a mapped in an eight-day interval consisting of missing values in Pattani Bay, Thailand from the year 2003 to 2017. This study further used the spline-fitted data for creating the baseline model of chlorophyll-a in Pattani Bay, and for examining the difference between spline fitted and monthly average data. This study revealed that the cubic spline method was able to handle the missing values in satellite data to gain the smoothness in data. When both models were compared, the spline-fitted observation yielded a smoother curve pattern than the monthly average observation. The spline fitted model was also able to display the chlorophyll-a data at any particular day of the year. It was also shown that the chlorophyll-a concentration level in the coastal area of Pattani Bay was higher in the inshore pixels, especially in rainy season.

Waste lubricant oil can be regenerated by flocculation and adsorption to get rid of impurities. In this work, the performance of flocculants (chitosan, sodium carbonate and sodium silicate) and sorbents (carclazyte and silica gel) were evaluated experimentally. The results showed that the combination of chitosan and sodium carbonate had beat results in removal of acid value and mechanical impurities. Silica gel contacting adsorption had the best colour removal. Thermal precipitation (80°C, 24h) was adopted as primary step before flocculation to wipe off heavier particulate matter. The best ratio of chitosan, sodium carbonate and silica gel was 1:1:1, and the best dosage of chitosan was 2% compared to oil. After the re-refining process, viscosity decreased from 186.34 (mm2/s, 40°C) to 155.21 (mm2/s, 40°C), the acid value from 0.26 (mg KOH/g) to 0.06 (mg KOH/g), mechanical impurities content from 3.62% to 1.41%, water content from 0.45% to 0.06%, and light absorbance from 4.31 to 1.17.

An extensive survey was carried out to understand the spatial distribution and possible sources of soil heavy metals in a phosphorus-rich area. A total of 615 topsoil samples were gathered, utilizing a regular sampling grid of 1×1 km squares, and the contents of arsenic (As), cadmium (Cd), cobalt (Co), chromium (Cr), copper (Cu), mercury (Hg), nickel (Ni), lead (Pb), vanadium (V) and zinc (Zn) were analysed to investigate the spatial distribution of these heavy metals, identify their sources, and assess levels of pollution. The results showed that the enrichment factor (EF) of the studied metals decreased in the order Cd > As > Pb > Co > Ni > Cr = Cu > Zn, and the mean contents of Cd, As and Pb were significantly higher than the background values. According to potential ecological risk (RI), 11.2% of the study areas had considerable potential ecological risk and the other areas had low to moderate potential ecological risk. The results of multivariate and geostatistical analyses indicated that Co, Cr, Ni and V, and to a lesser extent Cu and Zn, mostly originated from natural sources; while As and Pb, and to a lesser extent Cd, Cu and Zn, mainly originated from phosphorus-related industrial activities. The results also showed that Cd was affected by water with Cd pollution from the Hanjiang River. These results are useful for establishing policies for protecting local soil quality.

Today’s growing demand for energy has emphasized the need for the search for renewable resources. This demand can be met with by using alternative resources such as biofuel, rather than just depending on non-renewable resources. Therefore, the present study has been undertaken to extract lipid from a species of Bryophyta, i.e. Marchantia polymorpha. 0.044 g of lipid was extracted from 8 g of the bryophyte. Bligh and Dyer method was used for the extraction of lipid. It is a multi-step process in which methanol, chloroform, and NaCl play an important role in the extraction of bioproduct in the form of oily bodies. This small step taken towards energy utilization and conservation will open the new vista to mitigate the problem of energy crisis.

A novel type of NH2-functionalized carbon-coated Fe3O4 core-shell nanoparticles (Fe3O4@C-NH2) soil remediation agent was prepared. The effects of the Fe3O4@C-NH2 application rate, pH, water content, soil conductivity, soil organic matter (SOM) and solidification time on the solidification efficiency of cadmium (Cd) in Cd-contaminated soils were investigated. The results showed that the structure of Fe3O4@C-NH2 had a hollow core-shell, the carbon shell was well dispersed, the -NH2 bonding was obvious and the adsorption of Fe3O4@C-NH2 to Cd2+ in water quickly reached equilibrium within 20 min, with a saturated adsorption capacity of 78.83 mg.g-1. The Fe3O4@C-NH2 application rate and soil organic matter (SOM) had a great influence on solidification efficiency. SOM mainly affected the transition from weak acidity to reducible and oxidizable state, while solidification time affected the transition from oxidizable state to residual state. The optimal conditions for Fe3O4@C-NH2 solidification of Cd are: application rate of 3%-4% (3.3%), pH of 6-10 (7.33), moisture content of 40%-60% (50%), conductivity of 90-400 µS.cm-1 (142.6 µS.cm-1), SOM of 45.00-65.00 g.kg-1 (63.04 g.kg-1) and solidification time of no less than 10 days. Under the optimal conditions, the solidification efficiency of Fe3O4@C-NH2 for Cd was 42.95±1.89%, which significantly reduced the leaching and migration of Cd and achieved the goal of remediation.

Hybrid membranes are currently being developed to find the membrane that is having good chemical and thermal resistance. This research devotes to the development of hybrid membrane from clay/TiO2 with PVA polymer and its application for colour wastewater filtration. The results show that the optimum concentration of PVA is 5%. At this condition, the hybrid membrane has a bulk density of 2 g/cc and porosity of 23.13%. The hybrid membrane produces the coefficient rejection of 79.48%. At the higher concentration of PVA, the filtration becomes not effective because the flux of membrane is very low.

Olive mill wastewater (OMW) is a major problem in the olive oil producing countries, because of its highly polluting power. Its physico-chemical characterization showed that this effluent has an acidic character (pH = 4.9) and it is rich in organic and mineral matter (chemical and biochemical oxygen demands, polyphenols, chlorides, sulphates, nitrites, nitrates, etc.). In this work, the corrosion behaviour of carbon steel (X70) immersed in olive mill wastewater sample solution, collected from an agro-industry, was studied. The obtained results show that the rate of corrosion increases because of the attack of acids exist in the OMW (Cl-, polyphenols, Ni, Fe). For two days of immersion, the potential stretches toward more positive values due to the oxidization of carbon steel. After the extension of the immersion until 7 days, we recorded the formation of the corrosion product on the surface of the working electrode. On the other hand, the analysis of surface samples by scanning electron microscope coupled with EDX confirms the formation of a layer obtained after the corrosion process.

Based on the systematic collection of the shallow groundwater samples in the urban area of Suzhou, Anhui province, China, the concentrations of zinc have been analysed by statistical and spatial methods. The results show that the zinc concentrations in the groundwater samples are low, and all the samples can meet the national groundwater quality standard of China with Class I and II, which means that the groundwater can be used for drinking purpose. However, the zinc concentration has high coefficient of variation and low p-values of normal distribution, implying that it has been affected by anthropogenic activities, which was also demonstrated by the consistency of the distribution of the samples with high zinc concentrations and the areas with high density of human and transportation, as well as the high-high cluster of the spatial autocorrelation analysis of zinc. Based on the statistical analysis, the environmental background has been calculated to be 0-62.6 μg/L, whereas the environmental background has been calculated to be 0-69.8 μg/L with spatial analysis. They are different because of the different basis of the two methods, the former based on the hypothesis of normal distribution of the background values, whereas the latter do not need such a hypothesis.

Plankton diversity acts as an ecological indicator of aquatic ecosystems due to their rapid response to environmental changes. Plankton samples were collected monthly for a period of 24 months. A total of 35 genera of phytoplankton belonging to three classes, Bacillariophyceae (21 genera), Chlorophyceae (9 genera) and Cyanophyceae (5 genera) were found. The abundance of phytoplankton was in the order, Bacillariophyceae (83%) followed by Chlorophyceae (9%) and Cyanophyceae (8%). Maximum phytoplankton density in winter season was attributed to the low water temperature, gentle water velocity, high transparency, availability of sufficient nutrients and most stable substratum. Eight genera of zooplankton belonging to three major groups, Protozoa (2 genera), Rotifera (5 genera) and Copepoda (1 genus) was recorded. Shannon-Wiener diversity index of phytoplankton and zooplankton was computed maximum to be 2.61 and 1.56 respectively in the winter season. PCA indicates Cymbella, Navicula, Synedra, Cocconeis, Achnanthidium, Amphora, Nitzschia, Tabellaria, Fragilaria, Ulothrix, Spirogyra and Phormidium to be most dominant genera in the Mandakini river. Total alkalinity, water temperature, transparency, velocity, dissolved oxygen, free carbon dioxide, turbidity, phosphate and nitrate were found to be the most important factors affecting plankton diversity in the Mandakini river.