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Risk assessment and mitigation measures on the heavy metal polluted water and sediment of the Kolleru Lake in Andhra Pradesh, India Полный текст
2019
Das Sharma, S.
The Kolleru Lake is a famous Ramsar wetland of international significance. In this study heavy metal contents in water and sediment samples are reported. It is found that certain potentially toxic metal ions like chromium (4.5-80 µg/L), copper (1-20 µg/L), manganese (1-313 µg/L) and zinc (1.2-57 µg/L) are present in variable quantities in the lake water. When normalized with respect to concentration of each element in clean surface waters, the normalized ratio is found to be highly heterogeneous (chromium=4.5-80, copper=0.3-3.3, manganese=0.07-20.8, zinc= negligible to 2.8). At several places, the normalized ratio is greater than 1, indicating anthropogenic input. The concentration of iron (4-20 µg/L) in water, however, is less compared to the clean surface waters. Chemical analyses and quality assessment of Kolleru Lake sediments have been carried out through estimation of four pollution indices, which include enrichment factor (EF), geoaccumulation index (Igeo), contamination factor (CF) and pollution load index (PLI). Evaluation of these contamination indices with respect to average sediment composition of Taylor & McLennan (2001) confirmed that the Kolleru Lake sediment is polluted with a number of heavy metals that include cobalt (EF=2, Igeo=0.64, CF=2.4) , chromium (EF=1.5, Igeo=0.18, CF=1.7), copper (EF=1.6, Igeo=0.29, CF=1.9), manganese (EF=1.3, Igeo=0, CF=1.4), vanadium (EF=1.5, Igeo=0.19, CF=1.7) and zinc (EF=1.5, Igeo=0, CF=1.5). The level of contamination, however, is minor to moderate and is in good agreement with the heavy metal chemistry of the lake water. Based on these results some measures for environmental rehabilitation of the lake and its surroundings have been proposed.
Показать больше [+] Меньше [-]Efficiency of Washing Techniques for Removal of Heavy Metals from Industrial Sludge Полный текст
2019
J., Sumalatha | B. P., Naveen | R. K., Malik
The effluent treatment plant sludge is one of the major sources of contamination with toxic metals. Since the sludge contains heavy metals, it must be pretreated to reduce the contamination. The heavy metals from the sludge can be reduced/ separated by washing it with a suitable leaching solution. In the present study, the efficiencies of three leaching solutions to remove the contaminants from an industrial sludge were studied and the leaching process was modeled. The leaching solutions used are 0.1 N HCl, 0.1 N EDTA and 0.1 N FeCl3. The efficiencies of leaching solutions were assessed by conducting column leaching experiments on the sludge and the migration rates of heavy metal ions of Cu, Zn, Ni, Cd, Pb, Fe and Cr present in the sludge were estimated. These migration rates are useful to estimate the quantity of leaching solution required at the site to achieve the required levels of concentrations in the sludge.
Показать больше [+] Меньше [-]Investigation of Heavy Metal Contamination in the Surface Sediments of Anzali wetland in North of Iran Полный текст
2019
Shariati, S. | Pourbabaee, A. A. | Alikhani, H. A. | Rezaei, k. A.
Over the last few decades, Anzali wetland has been at risk of pollutants, especially from heavy metals. The present research analyzes some physical and chemical properties and heavy metals concentration in 27 points in nine stations of Anzali wetland. The samples of each station have been mixed, acidic digested, and analyzed by inductively coupled plasma mass spectrometry (ICP-MS). The mean concentrations of Fe, Mn, Pb, Zn, As, Cd, Cu, Hg, Ni, and Cr have been 50527.2, 1210, 23.3, 79.4, 8.8, 0.23, 32.1, 0.25, 31.6, and 31.5 mg/Kg, respectively. In addition, it can be seen that the concentrations of Cd (0.31 mg/Kg) and As (25.47 mg/Kg) in Hendekhale station, Hg (0.52 mg/Kg) in Pirbazar station, and Pb (52.69 mg/Kg) in Khazar villa station surpass world surface rock average. According to contamination factor (CF), in case of Mn and Pb, both Hendekhale, and Khazar Villa stations have been in considerable contamination level. The calculation of Pollution Load Index (PLI) shows that Hendkhaleh and Khazar Villa stations have had moderate pollution. The mCd index survey indicates that only in Hendekhale station, has heavy metals contamination been at a low degree level of contamination. According to PER index, mercury metal contamination in Hendekhale station faces medium risk. The calculated mean ERM quotient indicates the probability of heavy metals toxicity, equal to 21% in the examined stations.
Показать больше [+] Меньше [-]Influence of Copper Oxide Nanoparticle on Hematology and Plasma Biochemistry of Caspian Trout (Salmo trutta caspius), Following Acute and Chronic Exposure Полный текст
2019
Kaviani, E. F. | Naeemi, A. S. | Salehzadeh, A.
The Caspian trout is an endangered and quite vulnerable fish, considered for a natural protection program in the southern area of the Caspian Sea. Copper oxide nanoparticles (CuO-NPs) are toxic substances, which induce oxidative stress, not to mention other pathophysiological states. The toxicity of nanoparticles on fish needs more characterization for short- and long-term effects. Thus, the present paper examines the acute and chronic effects of CuO-NPs on hematology and plasma biochemistry of juvenile Caspian trout. After determining the lethal concentrations (LC50), juvenile Caspian trout is exposed to 0.1 LC5096 CuO-NPs for 28 days in three replicates. The blood samples are then collected from fish after 24, 48, 72, and 96 hours as well as 1, 2, 3, and 4 weeks of exposure to the CuO-NPsto deal with short- and long-term effects, respectively. Analysis of these samples shows that some hematological factors like hemoglobin (Hb), red blood cells (RBC), and hematocrit (Hct) are significantly increased after acute exposure, compared to the control group (p<0.05). The number of white blood cells (WBC), neutrophilis, and monocytes are also increased after acute and chronic exposure with significant differences (p< 0.05). Furthermore, the levels of lactate dehydrogenase after acute and alkaline phosphatase along with aspartate aminotransferase after acute and chronic exposure are significantly increased (p<0.05). Thus, results indicate that the presence of even a tiny amount of CuO-NPs can affect most haematological and metabolic enzymes of the Caspian trout in the short and long-term exposure. It is therefore essential to prevent these nanomaterials from entering the aquatic environment.
Показать больше [+] Меньше [-]Verification of IVE Model for SAIPA Co. Fleet Emission Полный текст
2019
Alipourmohajer, Sh. | Rashidi, Y. | Atabi, F.
To determine the amount of air pollutants, produced by Iranian automakers, and compare it with old and retrofitted vehicles have become one of the important tools of urban management. The present research uses International Vehicle Emission (IVE) modeling software in order to verify SAIPA Co. fleet emissions, based on Euro 4 emission standard (SAIPA Co. recognized as a superior Iranian brand in vehicle industry). There has been attempts to determine pollutant emission from Saipa Co.-manufactured cars in the city of Tehran, in accordance with Tehran Driving Cycle along with modeling and lab results which have over 90% conformity with modeling and lab results of New European Driving Cycle. According to ISQI’s 100,000-km test results, the amount of CO2 emission modeling from X100 and Tiba2’s has been about 160 gr/km, which has been within the range, whereas the modeled CO2 emission rate has been 232 gr/km in TDC, i.e., 1.5 times more than laboratory test, due to different driving cycle usage. Significant differences between the values obtained in the emission lab and modeling at New European Driving Cycle, Tehran Driving Cycle, and Tehran Air Quality Control Company report, indicate that relying on hypothetical situation leads to inapplicable emissions value from light vehicles.
Показать больше [+] Меньше [-]Influential Factors of Air Pollution Awareness in Isfahan, Iran Полный текст
2019
Yazdanibakhsh, F. | Salehi, E. | Faham, E. | Amin, M. M.
The main objectives of the present study are to both evaluate the level of awareness about air pollution and examine the determinants, likely to affect this awareness. As a result, it discusses influential factors on air pollution awareness, presenting findings from a case study, conducted in the city of Isfahan, Iran, wherein 400 individuals have been selected via proportional random sampling and the data has been collected by means of a questionnaire, provided by the authors, the validity of which has been confirmed by a panel of experts. As for the assessment of the questionnaire’s reliability, this study has used Cronbach's alpha to find out that it has been beyond 0.7 for all variables. The data have been analyzed, using descriptive and inferential statistics, such as the extent of mean, standard deviation, the coefficient of variation, correlation analysis, and regression analysis. Results from the latter show that level of education, level of using information sources, membership, motivation, and participation could explain 50% of the variations in the level of awareness concerning air pollution.
Показать больше [+] Меньше [-]Liquid Effluent Discharge and Control Management of Surrounding Soil Полный текст
2019
Hussein, H. M. | Ayub, S. | Siddiqui, A. A.
The effluent generated from a thermal power plant waste is a mixture of several chemicals and to identify the effect of these chemicals on soil, a case study on naturally contaminated sites at Al-Musayyib region, Hilla city in Iraq has been carried out. Soil and water samples were collected from the sites and analyzed to identify the pollutants and their effect on soil characteristics. Laboratory experiments were formulated to model the field around a channel collecting effluent for about 20 years and the pollutant transport pattern through the soil using soaking process was studied. Experiments were also conducted to study the effect of pollutants on engineering properties of the soil. For environmental management, permeable reactive barriers are used as stabilization and solidification technology to control the pollution through the soil. In this study, the suitability of locally available materials like activated granular carbon was also investigated as reactive media in permeable reactive barrier. The results have shown higher change in geo-environmental properties of soil with the soaking period and it has also been proved that granular carbon improves the geo-environmental properties of polluted soil.
Показать больше [+] Меньше [-]Simulating the Influence of Greenhouse Gases on the Climate of West Africa Полный текст
2019
Adeniyi, M. O. | Nymphas, E. F. | Oladiran, E. O.
The response of climate to perturbations in GHGs is location dependent. Six experiments: control (CTRL); double CH4; double CO2; double N2O; halved CFC11 and halved CFC12 were carried out to reveal the local area response to different GHGs levels in the atmosphere over West Africa. Double CH4, CO2 and N2O generally induce wetness but they also induce localized dryness at the hilly and mountainous areas of SW Ghana, Central Nigeria, Northern Cameroon and South-eastern Central African Republic. Increase in ground temperature is induced by double GHGs with intensified warming at the north by double CO2. However, patches of cooling are induced at the north. Changes in specific humidity induced by double CO2, CH4 and N2O are similar. Intensified tropical easterly jet is induced by double GHGs. A dipole anomaly of wind with positive at the lower latitude and negative at higher latitude is induced at the northern part of West Africa. Significant reduction in cloud water content is induced from 900 to 400 hPa and 0 and 15oN.
Показать больше [+] Меньше [-]Bioassessment of Heavy Metals in Wheat Crop from Soil and Dust in a Coal Mining Area Полный текст
2019
Maqbool, A. | X., Xiao | H., Wang | Bian, Z. | Akram, M. W.
Coal mining and related industry can increase heavy metals (HMs) concentrations in soil, atmosphere and wheat, thereby posing metal-associated human health risk via food ingestion. In this study, 58 samples of soil, wheat, and dust were collected from Xuzhou coal mine eastern China, six kinds of HMs Pb, Cd, Cu, Zn, As and Cr were studied for their spatial distribution in wheat, enrichment in different wheat organs (roots, stem leaf, glumes, and grains), pollution level and potential human health risks. Results show that the spatial distribution of HMs in wheat grains were likely to coal while dissimilar to soil. Most of heavy metals enrichment in wheat organs retained in glume and stem leaf after roots, and followed by grains, indicating that HMs was accumulated more from atmospheric dust as compared to other sources. Meanwhile, 71% of wheat grains were contaminated by HMs comprehensively in Xuzhou coal mine area. The potential health risk indicated that ingestion of food was the main exposure route causing non-carcinogenic and carcinogenic risk for inhabitants. This study provides basic information to control HMs enrichment from atmospheric dust and human health risk management policies in the mining area.
Показать больше [+] Меньше [-]Uptake of Some Elements with Aquatic Plants Exposed to the Effluent of Wastewater Treatment Plant Полный текст
2019
Tatar, S. | Obek, E. | Arslan Topal, E. I. | Topal, M.
In this study, in the removal of macro (P, S, Na, K, Ca, Mg) and micro (Sb, Ba, Co, Cu, Fe, Pb, Mn, Hg, Mo, Se, Ag, Zn) elements in the effluent of Elazig Wastewater Treatment Plant, the efficiency of Lemna minor L. and Lemna gibba L. has been studied comparatively. For this aim, fronds of these plants have been adapted to the effluent of the treatment plant that feeds pilot scale reactors. The concentrations of elements in fronds harvested during the working period were analyzed by ICP/MS. The analytical results show that Lemna minor L. has a high accumulation potential for P, Sb, Ba, Co, Fe, Pb, Mn, Hg, Ag and Zn while Lemna gibba L. has a high accumulation potential for S, Na, Ca, Mg, Cu, Mo and Se. The results show that Lemna minor L. and Lemna gibba L. can be used as phytoremediators of wastewater.
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