Organophosphorus compounds (OPs) are phosphoric acid derivatives represented by the formula (R2XP=O/S), R as organic groups; however, they need not contain a direct carbon-phosphorus bond. The organophosphorus compounds can be categorized into three classes, viz., organophosphates, carbamates nerve agents. The OPs having application as insecticides are generally phosphorothioates (i.e., containing P=S bond). These sulfur analogs are first bioactivated (in vivo) and converted to oxygen analogs responsible for exerting toxic action. These organophosphorus compounds are esters, fluorides, anhydrides, and amides of phosphoric, phosphorothioate, and phosphorodithioic acids. The toxicity of OPs is related to their molecular structure, metabolism in the targeted organisms, concentration, mode of decomposition, application, ingestion in organisms, etc. Exposure to OPs leads to the appearance of neurological symptoms followed by acute poisoning by targeting the target primarily, acetylcholine (AChE). However, secondary targets and other harmful effects besides nerve system problems are also reported. Organophosphates poison insects and other animals, including birds, amphibians, and mammals. These chemicals can have neural effects (Neurotoxicity), non-neuronal effects, or acute toxicity, which may also result in fatality. Their uncontrollable widespread became a significant threat to the environment; thus, corrective measures have been essential to save living beings and the environment from further damage.

Increased solid waste pollution and the negative effect of fossil fuel consumption on the environment are issues that would require more scientific attention and application to deal effectively with these phenomena. Wastepaper, a major component of solid waste, is classified as organic waste due to the presence of cellulose, a glucose-based biopolymer that is part of its structural composition. The saccharification of cellulose into glucose, a fermentable sugar, can be achieved with a hydrolytic enzyme known as cellulase. Although cellulase from fungal species such as Trichoderma, Aspergillus, and Penicillium are well described, knowledge about cellulase isolated from the brown garden snail is limited as it has not been the subject of many research endeavors. The waste paper has been described as a suitable resource for bio-energy development due to cellulose, a structural component of this bio-material that can be degraded into glucose, a fermentable sugar. Although paper materials such as newspaper, office paper, filter paper, Woolworths and Pick and Pay (retailers) advertising paper, as well as foolscap paper, were saccharified by different cellulases, the degradation of these paper materials by garden snail cellulase is a novel investigation from our laboratory. With the effects of temperature and incubation time on this cellulase action when degraded paper materials have already been investigated and reported, this study dealt with the garden snail cellulase action when degraded paper materials at different pH values. Most of the paper materials were degraded optimally at a pH value of 6.0, while optimum saccharification was observed at pH 4.5 when newspaper and brown envelope paper were degraded, with office paper showing maximum bioconversion at pH 7.0. The difference in the structural composition of the paper materials also affects the degree of saccharification, as the amount of sugar released from the various paper materials at optimum pH values is not similar. Together with other catalytic parameters, the pH value of this enzymatic catalysis is also to be considered when designing the development of waste paper as a bio-product resource, with limiting environmental pollution as an additional advantage of this process.

Rice farming plays a crucial role in maintaining national resilience and stability. However, its sustainability is faced with complex and multidimensional challenges. One of the challenges agricultural sustainability faces is the reduction of farmland due to the construction of toll roads. The development of the Solo-Mantingan-Ngawi toll road has significantly impacted the reduction of agricultural land in Sragen Regency, the second-largest rice-producing area in Central Java after Grobogan. This issue will threaten national food security if left unaddressed without further intervention. The development of sustainable agriculture is expected to be a solution to promoting food resilience. However, stakeholder involvement is necessary for successful development. This research aims to identify the stakeholders involved in developing sustainable agriculture to promote food resilience in Sragen Regency. This study adopts a mixed-method approach with data collection through in-depth interviews. The analytical tool used in this research is MACTOR (Matrix of Alliance and Conflict: Tactic, Objectives, and Recommendation). The study identified the stakeholders influencing the development of sustainable agriculture in Sragen Regency as Farmer Groups, Farmers, Village Heads, Agriculture Extenders, and the Department of Agriculture and Food Security. These findings serve as a basis for developing collaborative patterns among all stakeholders required to develop sustainable agriculture to achieve food resilience in the Sragen Regency.

It is extremely difficult to clean up accidental oil spills in water since conventional oil sorbents absorb much more water in addition to the oil. Alternatively, cleanup techniques might lead to secondary contamination. This study examines and measures the oil absorption capacities of two hydrophobic natural fibers: water hyacinth (Eichhornia crassipes) and lotus (Nelumbo nucifera). At the laboratory scale, the absorption of engine oil, vegetable oil, and diesel oils onto various dry biomass materials, including water hyacinth and lotus with different particle sizes (BSS-44, BSS-60, BSS-100, BSS-120, BSS-160, and BSS-200), was investigated. Water hyacinth shows a higher absorption efficiency for all samples as compared to the lotus.

Human beings experience adversative effects due to the large fluoride concentrations present in potable water. Because of the low cost and simple operation, the extensively acknowledged process is adsorption. The objective of this study is to investigate the performance of some of the prepared carbons from bio-waste materials viz., Citrus limon, Citrus nobilis, Pithecellobium dulce, and Bombax malabaricum sheaths in defluoridation. Initial concentration, particle size, agitation time, adsorbent dose, and pH were the different parameters chosen to study their effect on adsorption. Studied the adsorption kinetics. Further suitability to adsorption isotherms was reviewed.

The heavy metal speciation analysis in sediments helps us understand and evaluate essential and unavoidable issues in terms of both health and environmental hazards imposed by these metals in our lives. Analyzing the total content of heavy metals enables us to understand only the quantity of the contaminants. To understand the different species or the chemical forms of heavy metals available in the sediments, we must study their speciation. Speciation studies help us determine their possible sources as well as their environmental stability in terms of availability to plants and other organisms. The heavy metals in this study were specified using four-stage sequential extraction, also known as the BCR technique. This study mainly highlights the quantification of metal contamination of Cu, Zn, Pb, Ni, Cd & Cr, and chemical forms as species in sediment samples collected from different Pune District, Maharashtra sites. Heavy metal contamination from the collected samples was analyzed with the use of flame atomic absorption spectrometry. This study indicated that Zn and Ni are among the most abundant metals in the sediment samples; however, Cu and Cd belong to the least abundant category. The oxidizable and residual forms (immobile and cannot be used by the organisms readily) appeared dominant for most heavy metals. Very significant differences were observed in the speciation of heavy metals from sample to sample, which was probably due to differences in water/soil composition and the agrochemicals like pesticides, weedicides, and fertilizers used in agricultural practices; the wastewater generated from different pharmaceuticals, chemical processing and manufacturing industries as well as the improper wastewater treatment methods.

In the context of promoting high-quality development in the Yellow River Basin (YRB) of China, urgent action is needed to achieve the “Dual Carbon” goal through energy savings, emission reductions, and industrial upgrading. This study measures carbon emissions from eight types of energy consumption across 43 industries from 2000 to 2019. Using the Kaya-LMDI model, factors affecting carbon emissions are analyzed, and the relationship between industrial structure and carbon emissions is explored through the coefficient of variation (CV). The findings reveal that coal consumption remains significantly higher than other energy sources, and the effect of energy structure adjustment on carbon emission reduction is limited compared to the impact of energy consumption increase on carbon emission growth. Moreover, the economic output effect is identified as the primary driving factor of carbon emissions, while energy utilization rate is crucial in achieving energy savings and emission reductions. Finally, the CV of carbon emissions across 43 industries is increasing. Based on these results, we suggest several policy recommendations, including prioritizing ecological concerns, developing comprehensive and scientifically sound plans, optimizing energy consumption structure, improving energy utilization efficiency, and adjusting industrial structure to promote sustainable development in the YRB.

The current study is about detoxifying soil and water contaminated with toxic Cr(VI). To ensure that DAS1 could develop as well as possible, the pH was changed between 4 and 10. DAS1 showed its highest growth at pH 8, and at the same pH, it had an 85% potential to remediate by converting Cr(VI) to Cr(III). Immobilized bacteria increased the reduction of Cr(VI) to Cr(III) from the culture medium to 90.4%. The impact of glucose concentrations between 0.5 and 2.5 g.L-1 was examined. The greatest development was seen at pH 8 and 2 g.L-1 glucose concentration. The remediation potential was improved by up to 96% when the growing medium contained 200 mg.L-1 Cr(VI). The value of ks (0.434 g.L-1) demonstrated the substrate’s affinity for bacteria in accordance with the Monod equation, while μ max (0.090 h) demonstrated that DAS1 required 11.11 h for maximal growth. The multifactor experimental design was used to analyze mixed cultures of DAS1 and DAS2 in a 1:1 ratio, and it was determined that the X3Y2Z1 experiment design was best for completely removing Cr(VI) from the growing medium. By making pores using Na2EDTA, it was determined that the cell membrane’s impermeability did not cause Cr(VI) resistance in DAS1. The delayed lag phase indicated that the enzyme activity was inductive rather than constitutive.

A strategic shift towards sustainable, appropriate supply chain networks and data-driven decision-making in solid waste management in rural and urban areas can drastically reduce environmental pollution. This study utilizes a hybrid strategy of genetic algorithms and fuzzy logic to improve the supply chain network in solid waste management in Lagos State. In this research, four local governments in Lagos State are taken as a case study to help Identify solid waste in those selected areas, acquire data to better understand the supply chain network in solid waste management, and use the data acquired to model for the algorithm. A series of 30 iterations were carried out using a fitness parameter of frequency, price range, and means of disposal to determine who should be given utmost importance in the chain. Supply chains often exhibit inadequacies that may be enriched using Artificial Intelligence (AI) tools. The optimization model is flexible and useful, so everyone involved in the chain can coexist harmoniously. One of the reasons causing these inadequacies in proper waste management is a poorly planned supply chain network. It was concluded that the scavengers must be recognized as major participants in the movement of waste from houses to these provided refuse bins, with their frequency increased to 6 times daily with dustbins ranging from 9-20 be provided on each street which the private service participants (PSP).

In this study, we summarized our own and literature data on the helminth fauna in amphibians, reptiles, birds, and mammals inhabiting the Mordovia Nature Reserve (European Russia). The history of research on parasitic worms in vertebrates has more than 70 years here. Nowadays, 242 species of helminths have been identified in vertebrates in this protected area: 54 cestodes, 87 trematodes, 98 nematodes, and 3 acanthocephalans. Of these, 169 helminth species have an indirect life cycle, while 73 develop directly. 217 revealed parasite species use vertebrates as definitive hosts and 21 as intermediate and/or parathenic hosts. Three species of trematodes, Gorgoderina vitelliloba, Haplometra cylindracea, and Opisthioglyphe ranae combine the larval and mature lifestyle stages in amphibians. The most diverse helminth fauna is in rodents (41 species), birds (38), artiodactyls (37), and insectivores (35). Less rich in amphibians (32), bats (32), reptiles (26), and carnivores (19). Only six parasite species are found in hares. Most of the helminth species recorded in the vertebrates of the Mordovia Nature Reserve belong to the Palearctic faunistic complex – 107 species. Fifty-eight species are cosmopolitan. The range of 39 species covers the Holarctic. The distribution of 37 species of helminths is limited to Europe. Seventy-three of 242 species found in the nature reserve’s vertebrates have medical and veterinary importance as potential pathogens of dangerous zoonoses.