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A Novel Green Approach for Lead Adsorption and Isotherm Evaluation Полный текст
2023
M. Dharsana and J. Prakash Arul Jose
Environmental damage due to the discharge of organic pollutants and heavy metal toxins has become a major topic of concern for the past couple of years. Using just a natural adsorbent to solve wastewater concerns has lately gained popularity as an ecologically acceptable solution that encourages long-term growth. A range of approaches, including adsorption to the surface of agricultural leftovers, have been used to minimize heavy metals in an aqueous medium. Lead is amongst the most hazardous and widely discovered toxic substances in industrial waste. Citrus limetta peel powder, Banana peel powder, and Betel leaf powder were chosen as adsorbents in this study to absorb synthetic lead from an aqueous solution since they are low-cost materials. Our research aims to find natural bio-sorbents that can remove highly hazardous Pb2+ ions from aqueous solutions. The importance of contact time, concentrations, adsorbent-based dose, and pH in the adsorption process is investigated. The adsorption rate for betel leaves, Citrus limetta peel, and banana peel was 5, 10, 15, 20, and 25 g.L-1. Citrus limetta peel (10 g.L-1), banana peel (5 g.L-1), and betel leaf (5 g.L-1) provide the highest lead adsorption. Material characterization is used to determine the lead nitrate process in lead adsorption. The capacity of the lead-adsorbing substances to achieve adsorption equilibrium was assessed and estimated using linear Freundlich and Langmuir isotherms, with the experimental data fitting the Freundlich isotherm models.
Показать больше [+] Меньше [-]Forecasting Particulate Matter Emissions Using Time Series Models Полный текст
2023
S. Suresh, M. R. Sindhumol, M. Ramadurai, D. Kalvinithi and M. Sangeetha
Environmental pollution is a serious concern nowadays with its disastrous impact on living organisms. In several types of pollution, Air pollution takes on a crucial role by directly affecting the respiratory system and causing fatal diseases in humans. Air pollution is a mixture of gaseous and particulate matter interweaved by different sources and emanating into the atmosphere. In particular, particle pollutants are critical in growing air pollution in India’s main cities. Forecasting the particulate matter could mitigate the complications caused by it. The employment of a model to predict future values based on previously observed values is known as time series forecasting. In this paper, the PM2.5 pollutant emission data recorded at the Kodungaiyur region of Chennai city were forecasted using three-time series models. The standard ARIMA model is compared with the deep learning-based LSTM model and Facebook’s developed Prophet algorithm. This comparison helps to identify an appropriate forecasting model for PM2.5 pollutant emission. The Root Mean Squared Error (RMSE) acquired from experimental findings is used to compare model performances.
Показать больше [+] Меньше [-]Advanced Synthetic and Bio-Based Sorbents for Oil Spill Clean-up: A Review of Novel Trends Полный текст
2023
M. G. Gote, H. H. Dhila and S. R. Muley
Due to immense population growth and economic development, the use of crude oil for various energy applications has escalated in the past few decades. This has led to the large-scale exploitation of oil reserves which has further resulted in the accidental release of large amounts of oil into our oceans. In recent years, significant emphasis has been placed on processes involving oil sorption by various natural and synthetic sorbents. Several sorbent materials based on synthetic polymers such as polypropylene, polyurethane, polystyrene, etc., possessing three-dimensional porous structure, large surface area, high mechanical strength, and exhibiting good oil recoverability and reusability, have been employed for oil-water separation processes. Conversely, many of these materials in their native or pristine form are amphipathic, which prevents their large-scale use in oil spill clean-up. This has led to researchers exploring surface modifications of commercially available sorbent polymeric materials to enhance their oleophilicity and hydrophobicity. This review article summarizes and discusses recent advances in the strategies for the fabrication of newer surface-modified synthetic polymeric materials and natural bio-based sorbents, and further highlights their effectiveness in dealing with the oil/water separation challenges.
Показать больше [+] Меньше [-]Rethinking Waste Management in Indonesia Using Public-Private Partnership Framework: A Case Study of Akhmad Amirudin PET Bottle Waste Management Полный текст
2023
Akhmad Amirudin, Chihiro Inoue and Guido Grause
Municipal solid waste (MSW) continues to be a major challenge in almost every country. In Indonesia alone, approximately 64 million tons of MSW are produced on an annual basis. While polyethylene terephthalate (PET) bottles account for 12% of all plastic products, the waste is not well managed. Many stakeholders are involved in PET bottle waste recycling but no forum for stakeholders has been established. In this study, the aim is to identify an acceptable system for PET bottle waste, to determine the role and function of each stakeholder, and to propose a framework under the perspective of public-private partnerships. The study’s novelty is the elaborate roles and schematic framework for various stakeholders in PET bottle waste. The aim is to identify an acceptable scheme for PET bottle waste and determine each stakeholder’s role and function. Data was generated from electronic databases (2017 to December 2021) a systematic literature review methodology followed by Preferred Reporting Items for Systematic review. The data were analyzed by the Meta-Analysis (PRISMA) approach. This study found that the laws and regulations for waste management in Indonesia are not suitable for dealing with PET bottle waste, and the government carries out limited tasks and dedicates few resources to managing the waste. A public-private partnership framework was proposed to divide the role, commitment, goal, and activities of each stakeholder to properly manage PET bottle waste.
Показать больше [+] Меньше [-]Utilization of Waste Glass for Enhancement of Chemical Properties of Concrete Полный текст
2023
Jagriti Gupta, A. S. Jethoo and Nandeshwar Lata
The world is facing a huge problem of waste generation; among these, solid waste in the form of glass has become a prime concern for the environment. The composition of the glass is silica-based, and its utilization in the preparation of concrete can be an efficient step in the direction of sustainable development by reducing the cement content. The formation of secondary calcium silicate hydrates (C-S-H) could take place due to the pozzolanic reaction of the fine ground glass with the cement. TGA techniques were used in this research to investigate the chemical properties of the waste glass, and later, these were compared with the properties of the cement. By keeping a constant w/b ratio for all the replacement levels from 0% to 35%, the evaluation of the workability and compressive strength were done. The evaluation showed that workability increased with an increase in the content of the waste glass. With 7 and 28 days cured samples, the strength and chemical investigation were conducted on the samples prepared with the same mix design. Constant Dose of superplasticizer used by weight of cement for mixes as 0.8%. Compared with the control sample, The level of replacement of waste glass to cement as 30% has depicted the augmentation in the compressive strength. Thus, the use of waste glass was found to be cost-effective and an environment-friendly solution for the sustainable development of concrete.
Показать больше [+] Меньше [-]Heavy Metal Removal from Contaminated Soil Using Soil Washing Techniques Полный текст
2023
G. Resmi, Santosh G. Thampi and S. Chandrakaran
Heavy metals are discharged into the soil around us from various anthropogenic sources and also by the use of fertilizers, pesticides, pharmaceuticals, etc. In most cases, industrialization can be pointed to as the reason behind soil pollution. Contamination of soil leads to large-scale environmental degradation and health impacts. Many investigators have studied techniques for removing heavy metals from soil. Soil washing is an emerging area that can be implemented for this purpose. Studies were carried out in the controlled conditions of a laboratory environment to determine the suitability of soil-washing techniques for removing lead from polluted land. The results showing the influence of various parameters in soil washing, such as duration of washing, molar strength of the solution used, the weight ratio of soil to wash solution, etc., are presented in this paper. Batch studies were conducted to investigate the performance of chelating agents such as Na2EDTA, HCl, HNO3 and CaCl2 with regard to the removal of lead from artificially contaminated locally available soil. Based on the batch studies, it is observed that the strength of the washing solution, the proportion of soil and solution, the period of agitation, etc. influence the removal of contaminants. Based on the studies, it is concluded that, while recommending soil washing using chelating agents for remediating lead-contaminated soils, it is essential to identify the influencing parameters and determine the optimum conditions so that higher removal can be achieved without any adverse effect.
Показать больше [+] Меньше [-]Influence of Different Particle Sizes of Sediments on the Lower Reaches of the Basin and its Significance in the Liao River Governance Полный текст
2023
Chen Yang
Based on the sand volume and sedimentation volume data for different particle size (PS) groups, the relationship between the annual scouring and silting amount of the Juliu River-Liujianfang section and the yearly sediment volume entering the downstream river channel was established. The critical values of sediment storage and release for the downstream river channel were obtained. It was found to decrease with an increase in the sediment particle size. The correlation coefficient between the annual scouring and silting amount of the Juliu River-Liujianfang section and the annual sediment volume entering the downstream river channel increased with the coarsening of sediment PS. It indicated that the sediment size was proportional to the sediment amount (SA) entering the river channel. As the sediment size increased, the deposition amount increased due to the variation of unit sediment amount. Based on the treatment and achievement of source areas with sediment sizes larger than 0.05 mm, it is significant to concentrate on treatment areas with sediment sizes larger than 0.10 mm.
Показать больше [+] Меньше [-]An Integrated GIS-AHP Approach for Municipal Solid Waste Landfill Siting in Srikakulam District, Andhra Pradesh Полный текст
2023
Penki Ramu , Basina Sai Santosh and Praveen S.
The availability of land for proper waste disposal is one of the most important and emerging potential challenges in most big cities. Although some attempts are being made to minimize and recover garbage, landfill disposal continues to be the dominant method of waste disposal. An improper landfill site can negatively impact the environment, the economy, and the environment. Thus, it should be carefully chosen, taking into consideration both rules and standards from other sources. To examine all aspects of this study, an integration of the “Geographic Information System (GIS)” and the “Analytic Hierarchy Process (AHP)” was incorporated for land-fill site selection. Various parameters were examined to make decisions about landfill site selection. These parameters included slope, elevation, soil texture, LULC, surface water, groundwater table, road network, historical areas, and residential areas. An analytic-hierarchy process was used to determine the relative importance of each parameter, and a final site suitability map was created. With an equal interval classification method, the final index model was categorized into four categories, which included “unsuitable”, “less suitable”, “moderately suitable” and “suitable”. As a result, 30.28% of the study area was less suitable, 28.49% was moderately suitable, 12.39% was suitable, and 28.84% of the study area was unsuitable for landfilling.
Показать больше [+] Меньше [-]Pattern Characterization of Meteorological Drought Using Multivariate Drought Index Over Mirzapur in Middle Gangetic Plains of India Полный текст
2023
Shivani Gond, Nitesh Gupta, P. K. S. Dikshit and Shyam Bihari Dwivedi
Droughts and floods have been occurring at a higher frequency in recent decades. The rapid transition between them magnifies the socio-economic consequences of these catastrophes relative to the effects of the individual occurrences of the extreme event. This study examines the temporal variability of meteorological drought and wet event characteristics occurring over Mirzapur (Uttar Pradesh), India. The Standardized Precipitation Evapotranspiration Index (SPEI) is applied to monthly water balance at scales 3, 6, 9, and 12 months to estimate the meteorological drought and wet events from 1971 to 2018. Drought and wet event characteristics such as the number of drought/wet events, severity, duration, and intensity are estimated using run theory over SPEI output. While characterizing the pattern of trends over the historical time period, variable-sized cluster analysis (VSCA) allows the detection of multiple change points as opposed to the Mann-Kendall (MK) test, which produces a monotonic trend for the entire time period. The VSCA technique accounts for drought variability and depicts the pattern’s evolution across the period under consideration. Station-scale drought data from Mirzapur, Uttar Pradesh (UP), India, were used in the procedure. VSCA allows for the detection of many change points while describing the pattern of drought trend throughout a historical period, as opposed to the usual Mann-Kendall (MK) test, which provides a monotonic trend for the whole time. As a result, VSCA demonstrated the MK test compatibility.
Показать больше [+] Меньше [-]Research on the Law of Stress of Polychlorinated Naphthalenes (PCNs) on the Physiological Ecology of Bluegrass (Poa annua L.) Полный текст
2023
Chen Laiyi, Song Yundi, Li Yue, Jiang Lei, Wang Yi, Wang Song and Hou Wei
This paper takes Poa annua L. as the research object and studies the law of physiological and ecological stress of 1-Chloronaphthalene (CN-1) and Octachloronaphthalene (CN-75) by using various physiological and biochemical indexes of Poa annua L. cultivated with soil under the stress of CN-1 and CN-75 of different concentrations. According to the research, the chlorophyll a and b first increase and then decrease with the increase of the concentration of CN-1, and continue to decrease with the increase of CN-75; Soluble sugar and soluble protein in plants decrease first and then increase with the increase of CN-1, and continue to decrease with the increase of CN-75; MDA in plants increases first and then decreases with the increase of the concentration of CN-1 and CN-75. The proline content in plants also increases first and then decreases with the increase of concentration of CN-1 and CN-75. Based on the research, it can be seen that the tolerance of the plant to CN-75 is not good as to CN-1.
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