The fragmentation of plastic materials into nanoparticles of less than 1000 nm (secondary nanoplastics) and their possible accumulation in the environment is a recent matter of concern. There are still no suitable standard methods for determining the concentrations and chemical makeup of these particles in aquatic systems and the fate and effect of nanoplastics in the aquatic environment has been little explored, although there has been research using engineered nanoparticles as models. In this review, we give a summary of the (mainly laboratory-based) studies on the influences of nanoplastics. We aim to provide an updated overview of this emerging topic, reviewing the literature mainly from 2018 onwards and considering the effects of nanoplastics on ecosystems, their uptake and transport of polluting molecules, and the challenges that are faced by workers in this area. The review includes 119 references.

Ammonia (NH₃) emissions, the majority of which arise from livestock production, are linked to high concentration of PM₂.₅ and lower air quality in China. NH₃ mitigation options were well studied at the small-scale (laboratory or pilot), however, they lack of a large-scale test in China. This study fills this crucial gap by evaluating the cost-benefit of pioneering NH₃ mitigation projects carried out for a whole county – Sheyang, Jiangsu province, China. Measures were implemented in 2019 following two distinct strategies, improved manure treatment for industrial livestock farms, and collection and central treatment for traditional livestock farms. Emission reductions of 16% were achieved in a short time. While this is remarkable, it falls short of expectations from small-scale studies. If measures were fully implemented according to purpose and meet expectations from the small scale, higher emission reductions of 42% would be possible. The cost benefit analysis presented in this study demonstrated advantages of central manure treatment over in-farm facilities. With improved implementation of mitigation strategies in industrial livestock farms, traditional livestock farms may play an increasing role in total NH₃ emissions, which means such farms either need to be included in future NH₃ mitigation policies or gradually replaced by industrial livestock farms.The study found an agricultural NH₃ reduction technology route suitable for China's national conditions (such as the “Sheyang Model”).

Japan receives nitrogenous air pollutants via long-range transport from China. However, emissions of nitrogenous air pollutants in China have stabilized or decreased in recent years. This study examined both the long-term trends in atmospheric nitrogen (N) deposition from the 1990s to the 2010s and the response of stream water nitrate (NO₃⁻) leaching from forested areas in western Japan. A long-term (1992–2018) temporal analysis of atmospheric N deposition in Fukuoka (western Japan) was conducted. Atmospheric bulk N deposition was collected at forested sites in a suburban forest (Swₑₛₜ) and a rural forest (Rwₑₛₜ) in western Japan during 2009–2018. Stream water samples were also collected from four locations at sites Swₑₛₜ and Rwₑₛₜ during the same period. Results showed that atmospheric N deposition in Fukuoka started to decrease from the mid-2000s at an annual rate of −2.5% yr⁻¹. The decrease in atmospheric N deposition was attributable mainly to decreased atmospheric ammonium (NH₄⁺) deposition, which caused greater contribution of NO₃⁻ deposition to atmospheric N deposition. Concentrations of NO₃⁻ in the stream water samples from three of the four locations decreased significantly at an annual rate of −3.7 to −0.7% yr⁻¹. However, stream water NO₃⁻ concentrations increased in one watershed where understory vegetation has been deteriorating owing to the increased deer population. This might weaken the recovery of N leaching from forested areas.

Source apportionment can be an effective tool in mitigating soil pollution but its efficacy is often limited by a lack of information on the factors that influence the accumulation of pollutants at a site. In response to this limitation and focusing on a suite of heavy metals identified as priorities for pollution control, the study established a comprehensive pollution control framework using factor identification coupled with spatial agglomeration for agricultural soils in an industrialized part of Zhejiang Province, China. In addition to elucidating the key role of industrial and traffic activities on heavy metal accumulation through implementing a receptor model, specific influencing factors were identified using a random forest model. The distance from the soil sample location to the nearest likely industrial source was the most important factor in determining cadmium and copper concentrations, while distance to the nearest road was more important for lead and zinc pollution. Soil parent materials, pH, organic matter, and clay particle size were the key factors influencing accumulation of arsenic, chromium, and nickel. Spatial auto-correlation between levels of soil metal pollution and industrial agglomeration can enable a more targeted approach to pollution control measures. Overall, the approach and results provide a basis for improved accuracy in source apportionment, and thus improved soil pollution control, at the regional scale.

Mean oceanic CO₂ values have already risen and are expected to rise further on a global scale. Elevated pCO₂ (eCO₂) changes the bacterial community in seawater. However, the ecological association of seawater microbiota and related geochemical functions are largely unknown. We provide the first evidence that eCO₂ alters the interaction patterns and functional potentials of microbiota in rearing seawater of the swimming crab, Portunus trituberculatus. Network analysis showed that eCO₂ induced a simpler and more modular bacterial network in rearing seawater, with increased negative associations and distinct keystone taxa. Using the quantitative microbial element cycling method, nitrogen (N) and phosphorus (P) cycling genes exhibited the highest increase after one week of eCO₂ stress and were significantly associated with keystone taxa. However, the functional potential of seawater bacteria was decoupled from their taxonomic composition and strongly coupled with eCO₂ levels. The changed functional potential of seawater bacteria contributed to seawater N and P chemistry, which was highlighted by markedly decreased NH₃, NH₄⁺-N, and PO₄³⁻-P levels and increased NO₂⁻-N and NO₃⁻-N levels. This study suggests that eCO₂ alters the interaction patterns and functional potentials of seawater microbiota, which lead to the changes of seawater chemical parameters. Our findings provide new insights into the mechanisms underlying the effects of eCO₂ on marine animals from the microbial ecological perspective.

Cadmium (Cd), as an environmental pollutant, can lead to nephrotoxicity. However, its nephrotoxicological mechanisms have not been fully elucidated. In this study, Cd (1.5 mg/kg body weight, gavaged for 4 weeks) was found to induce the renal damage in mice, based on indicators including Cd concentration, kidney index, serum creatinine and blood urea nitrogen levels, pro-inflammatory cytokines and their mRNA expressions, levels of Bcl-2, Bax and caspase9, and histopathological changes of the kidneys. Furthermore, Cd-caused detrimental changes through inducing inflammation and apoptosis via the miR-34a/Sirt1/p53 axis. This is the first report on the role of miR-34a/Sirt1/p53 axis in regulating Cd-caused apoptosis and nephrotoxicity in mice. The findings obtained in this study provide new insights into miRNA-based regulation of heavy metal induced-nephrotoxicity.

Air pollution caused by PM₂.₅ particles is a critical issue for public health that adversely affects people living in urban cities. Short-term Mega-events such as international meetings, sports tournaments, and traditional festivals can profoundly influence the local air quality. However, the extent of these influences and their role in improving or deteriorating the local air quality is still unclear. By collecting relative research from 75 publications based on more than 37 cities worldwide, we conducted a systematic review and meta-analysis. We calculated the log response ratio (RR) of the treatment (during) and control periods (before and after) of the Mega-events. The short-term policy control measures enacted during the Mega-Events consisting of meetings caused a significant decline (by −44.06%) in the ambient PM₂.₅ concentration. The mean daily PM₂.₅ concentration reduced from more than 100.00 μg/m³ before the events to 60.39 μg/m³, which is below the WHO (World Health Organization) interim target – 1 (75 μg/m³). On the contrary, setting off fireworks during the festival increased the ambient PM₂.₅ concentrations by 89.57% on average, with a mean daily value of 254.22 μg/m³. The variations in the effects of all event types on the air quality were primarily influenced by the background PM₂.₅ concentrations, with a negative correlation throughout. Moreover, the impact of events with policy control measures was also influenced by the year of the event, level of control, and location (suburban/urban) of the monitoring sites. Our findings provide evidence of the potential of human intervention on PM₂.₅ pollution reduction. We further highlight the crucial role of background pollution level in implementing policies during the Mega-events, which can benefit the environmental governance of developing countries.

Deca-brominated diphenyl ether (BDE-209) is shown to be persistent in soil and it's urgent to find an effective method to remove BDE-209 from contaminated soil. In this study, the investigation of BDE-209 degradation in three different rice-vegetable rotation soils induced by electron beam (E-beam) irradiation under flooded and non-flooded conditions was conducted. The reductive efficiency of ¹⁴C-BDE209 reached the highest level at 50 kGy and the values in flooded soils of rice-eggplant rotation soil (RES), rice-peanut soil (RPS), and rice-chili pepper soil (RCS) were 93.5%, 87.2%, and 73.8%, respectively. The reductive efficiencies in non-flooded soils of RES, RPS, and RCS were 73.4%, 81.0%, and 78%, respectively. The D₀.₅ values (dose required for reducing 50% BDE-209) of BDE-209 in non-flooded soils were lower than those in flooded soils, suggesting greater degradation efficiency of BDE-209 in non-flooded soils than in flooded soils. The BDE-209 was degraded into higher-brominated PBDEs and lower-brominated PBDEs by E-beam irradiation. The results demonstrate that BDE-209 in the soil can be degraded by E-beam irradiation, non-flooded condition is better than flooded condition for the removal of BDE-209, and the main degradation mechanism of BDE-209 by E-beam irradiation is debromination. This study provides a rapid and effective method for degrading BDE-209 that is persistent in soils, and has important implications for the remediation of soil contaminated by PBDEs in and around E-waste dismantling areas.

Vehicle emission is an important source of ammonia (NH₃) in urban areas. To better address the role of vehicle emission in urban NH₃ sources, the emission factor of NH₃ (NH₃-EF) from vehicles running on roads under real-world conditions (on-road vehicles) needs to update accordingly with the increasingly tightened vehicle emission standards. In this study, laser-absorption based measurements of NH₃ were conducted during a six-day campaign in 2019 at a busy urban tunnel with a daily traffic flow of nearly 40,000 vehicles in south China’s Pearl River Delta (PRD) region. The NH₃-EF was measured to be 16.6 ± 6.3 mg km⁻¹ for the on-road vehicle fleets and 19.0 ± 7.2 mg km⁻¹ for non-electric vehicles, with an NH₃ to CO₂ ratio of 0.27 ± 0.09 ppbv ppmv⁻¹. Multiple linear regression revealed that the average NH₃-EFs for gasoline vehicles (GVs), liquefied petroleum gas vehicles, and heavy-duty diesel vehicles (HDVs) were 18.8, 15.6, and 44.2 mg km⁻¹, respectively. While NH₃ emissions from GVs were greatly reduced with enhanced performance of engines and catalytic devices to meet stricter emission standards, the application of urea selective catalytic reduction (SCR) in HDVs makes their NH₃ emission an emerging concern. Based on results from this study, HDVs may contribute over 11% of the vehicular NH₃ emissions, although they only share ∼4% by vehicle numbers in China. With the updated NH₃-EFs, NH₃ emission from on-road vehicles was estimated to be 9 Gg yr⁻¹ in the PRD region in 2019, contributing only 5% of total NH₃ emissions in the region, but still might be a dominant NH₃ source in the urban centers with little agricultural activity.

In this report, we investigated the accumulation of heavy metals in the lizard Microlophus atacamensis, in three coastal areas of the Atacama Desert, northern Chile. We captured reptiles in a non-intervened area (Parque Nacional Pan de Azúcar, PAZ), an area of mining impact (Caleta Palitos, PAL) and an active industrial zone (Puerto de Caldera, CAL). Our methods included a non-lethal sampling of reptiles’ tails obtained by autotomy and a few sacrificed animals to perform a stomach contents analysis. The concentrations of lead, copper, nickel, zinc and cadmium were measured by atomic absorption spectrophotometry in both soil and prey and compared to those recorded in the lizards’ tails. Data obtained from lizard tails captured in PAL showed significantly high concentrations of Pb, Cu, Ni, and Zn compared to the other two sites PAZ and CAL. We did not find statistically significant differences among PAZ, PAL and CAL soils, probably due to the similar geological composition of the sites. However, the regional background values for Pb indicate contamination or at least metal enrichment in soils of the three sites, for Cu the global background values indicate contamination for the three sites, and for Cd both the regional and global backgroud values show high values. The analysis of the stomach content showed differences in the food sources of the lizards among the sites studied. The concentration of heavy metal in lizard tissues versus prey delivered values of the Trophic Transfer Factor higher than one (1), suggesting that food may be a primary source of metals in the tissues of M. atacamensis. Calculations of the Bioaccumulation Factor (BAF) and the Ecological Risk (IR) resulted in values higher than one (1) indicating the relevance of this process in the sites studied. In this article, we report relationships between environmental contaminants, mainly putative preys, and concentrations found in lizard tails, which is more substantial in areas with historical heavy metal contamination such as PAL where the non-lethal technique developed in this research suggests a process of metal bioaccumulation in M. atacamensis.