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Prioritizing Local Biomass Resources for Biofuel Production by a Fuzzy Hybrid Decision Making Approach (The Case of Hormozgan Province in Iran) Полный текст
2023
nohegar, Ahmad | Alavi Naeini, Mina | Alavi naeini, Ali
In recent years, increasing in energy demand and the importance of using energy with minimum green- house gas emission (GHG) leads researchers to study about renewable energy resources such as biomasses. Biomasses can be converted to biofuels by applying the appropriate technologies. In this study, a hybrid group fuzzy multi-criteria decision making (MCDM) approach based on step-wise weight assessment ratio analysis (SWARA), technique for order preference by similarity to ideal Solution (TOPSIS), additive ratio assessment (ARAS), weighted aggregated sum product assessment (WASPAS) and simple additive weighting (SAW) in the fuzzy environment is applied to rank biomasses in the case of Hormozgan province in Iran, because of being a coastal area and the access to different types of first, second and third generation resources of biofuel. After ranking these resources by mentioned methods, two aggregated multi-criteria decision making (MCDM) methods (mean rank method and Copeland method) are employed to prioritize these biomasses. Results of mean rank show that municipal solid wastes (MSW), fish wastes and microalgae have the minimum average rank, respectively and the results of Copeland method show that MSW, fish wastes and microalgae have the maximum (wins-loses), respectively. So, these biomasses are the most suitable ones in biofuel production in this province.
Показать больше [+] Меньше [-]Assessment of some Heavy Metals and Health Risks in Water and Shrimps from a Polluted Mangrove Swamp, Niger Delta, Nigeria Полный текст
2023
Davies, Davies, Ibienebo Chris | Anyanwu, Emeka
The heavy metal concentrations of water and shrimp (Penaeus monodon) from Isaka Bundu swamp, Niger Delta were evaluated between January and June 2022. The non-carcinogenic health risk assessment was used to assess the water's suitability for recreation and the shrimps for consumption. Five heavy metals (Pb, Cu, Cd, Ni, and Zn) were assessed in both media using standard methods and compared with national and international standards. The Chronic daily intake (CDI) for Cd and Cu (in children) exceeded their respective reference doses while hazard quotients (HQs) for Cd and Cu (in children) and all the hazard indices were greater than 1 in the water. All the target hazard quotients (THQs) and total hazard index (THIs) were lower than 1 in the shrimps. The heavy metal concentrations, CDIs, HQ/THQs and HI/THIs were higher in the more impacted stations 1 and 3. Based on the heavy metal concentrations and health risk assessment, the waters of the Isaka Bundu swamp are unsafe for recreational purposes. However, shrimps are safe for human consumption. The high concentrations of heavy metals in the water influenced the concentrations in the shrimps. Anthropogenic activities in the area contributed to the heavy metal concentrations in the environment. The results also showed that the children were more prone to adverse health impacts.
Показать больше [+] Меньше [-]Feasibility of Production of PET/ZIF-8 Polymer Media to Remove Particles from the Air Stream Compared to HEPA Filter Полный текст
2023
Kazemi, Meghdad | Kalantary, Saba | Abbasi, Ali Reza | Rahimi Foroushani, Abbas | Golbabaei, Farideh
Polyethylene terephthalate (PET) and Zeolitic Imidazolate Framework-8 (ZIF-8) were used to investigate the feasibility of producing electrospun PET/ZIF-8 polymer media in removing particles from the air stream to compare with the HEPA filter. To make PET/ZIF-8 media, concentrations of 0.5, 1, 2.5, and 5 wt.% of ZIF-8 were dissolved in PET20% solutions, and dispersed for 10 min. Then, PET/ZIF-8 media was produced with an ESDP30 model electrospinning device. The efficiency and pressure drop of nanofiber media were measured with a respiratory mask and filter test device. The FTIR, XRD and SEM analysis were carried out to obtain the characteristics of nanofibers. The overall XRD pattern and its peaks were in reasonable agreement with previous findings that confirmed the structure of ZIF-8. The FTIR spectra of the obtained materials confirm that the chemical bond structure corresponds to that reported for ZIF-8. In total, The PET/ZIF-8(1%) media efficiency, pressure drop, the average diameter of nanofibers, and the quality factor were 100%, 320 Pa, 171.18±37.91 nm and 0.0143 Pa-1, respectively, which was better than other electrospun PET/ZIF-8 media and HEPA filters. According to the results, with an increase in the weight percentage of Zif-8 (>5 wt.%) in the structure of PET/Zif-8 media, due to the increase in the viscosity of the solution jet, the diameter of the produced nanofibers increased and the efficiency of the electrospinning medium decreased.
Показать больше [+] Меньше [-]Dust Emission Calculation and Forecasting using CALPUFF and GCM models Полный текст
2023
Tamjidi, Mahsa | Abbaspour, Madjid | Rashidi, Yousef | Mirzahosseini, Alireza
Dust is an important atmospheric phenomena that occurs in spring and summer in many regions, including Iran and its neighboring countries. Considered one of the most important challenges of the last century, this phenomenon occurs on a global scale in arid and semi-arid regions. Because of changes in climate and vegetation as well as progressive processes of soil erosion and the disturbances resulting from them, the sensitivity of regions to rapid erosion will have important reactions on the region's climate and desertification. Therefore, the current research investigated the concentration and distribution of fine dust under the influence of meteorological parameters using the GCM climate model and attempted to determine the effect of climate change on the concentration of the relevant pollutant in the coming years. In this study, the CALPUFF model considered the temporal and spatial effects of weather conditions on the transfer, transformation, and removal of atmospheric pollutants. The emission rate of the PM10 pollutant was estimated. The results indicated that the increase in greenhouse gas emissions and changes in climate variables in the near future will cause the distribution of suspended particles one of the important pollutants to increase significantly. The results also revealed a significant relationship between the degradation of air quality and the trend of air warming during the period 2046-2065.
Показать больше [+] Меньше [-]The Effects of Seasonal Changes of Ambient Temperature and Humidity on Exhaust Pipe Emissions and Greenhouse Gases Полный текст
2023
Hoseinifar, Seyed Erfan | Shafiepour Motlagh, Majid | Ashrafi, Khosro | Ahadi, Mohammad Reza
This article provides an overview of the main findings of a survey on the effects of ambient temperature and humidity on vehicular emissions of criteria pollutants and greenhouse gases. The present study is focused on the emissions of Carbon Monoxide (CO), Nitrogen Oxides (NOX), Sulfur Oxides (SOX), Particulate Matters (PM), Carbon Dioxide (CO2), Nitrous Oxide (N2O), and Methane (CH4) from gasoline engine passenger cars. In this analytical research, the International Vehicle Emissions (IVE) model was operated, using long-term meteorological data to determine the effects of various ambient temperature and humidity levels on exhaust pipe pollutants and greenhouse gas emissions. The results of present study indicated that as the ambient temperature increases from -7.5 °C to 20 °C, CO, NOX, and CH4 emissions decrease by 35.8%, 6.46%, and 21.44%, respectively, while SOX, PM, CO2, and N2O emissions remain constant. In contrast, increasing the ambient temperature from 20 °C to 37.5 °C increases the emissions of all the investigated pollutants and greenhouse gases. On the other hand, the findings showed that as the ambient humidity increases from 8% to 98% CO and CH4 emissions increase by 7.3% and 2.13%, respectively; while NOX emissions decrease by 16.84%. However, humidity changes did not have noticeable impact on the emissions of SOX, PM, CO2, and N2O. This study concluded that changes in meteorological parameters over a certain period of time, not only affect global warming, but also the emissions of criteria pollutants.
Показать больше [+] Меньше [-]Detection of Microplastics in Drinking Water Treatment Plants in Baghdad City/Iraq Полный текст
2023
H. Sultan, Hassan | Abdul Wahab Shaker Al-Aadhami, Mohammad | Nihad Baqer, Noor
Microplastics are an emerging environmental pollutant detected in different environments, but studies in Iraq are rare, if not nonexistent. Our research aims to detect the presence of microplastics in raw water and drinking water treatment plants in Baghdad. Water samples were collected (1 liter per sample) from four drinking water treatment plants: Al-Fahama station, Al-Fath Al-Mubin station, Al-Dora station, and Al-Madaen station, which receive water from the Tigris River. The microplastic shape was determined by a fluorescent microscope examination after staining with Nile dye. FTIR spectrophotometer used to determine microplastic compounds. The results showed, according to FTIR examination, that the most critical types of microplastic compounds in water samples were Nylon, Polycarbonate, High-density polyethylene, Polystyrene, Polyamide, Polyethylene terephthalate, and Polyurethane, and Microplastics number were (17-62 MPs /L) in raw water, while in drinking water were (9-40 MPs/L). The fibers form is the predominant form of microplastics in natural and drinking for stations: Al-Fahamah (91.6%, 66.6% respectively), Al-Fath Al-Moubin (58.8%, 77.7% respectively ), Al-Doura (65.3%, 52.5% respectively), Drinking water in Al-Madaen station (40.0%). At the same time, the spherical shape is predominant in the raw water of Al-Madaen station (82.2%).In conclusion, the current study indicated the pollution of drinking water treatment plants with microplastics.
Показать больше [+] Меньше [-]Cold plasma Technology for Removal of Endotoxin from Dialysis Water Полный текст
2023
Fakhri Jasim, Shaimaa | Raad Humudat, Yasamen | Awad Kadhim, Suadad
Cold plasma has emerged as a powerful energy-efficient and environmentally friendly advanced oxidation technique in recent decades as a non-thermal approach in a wide range of applications. It is a form of plasma that is created at low temperatures and can be used for various applications, including water treatment This study aims to determine the influence of Cold plasma treatment on endotoxin reduction in dialysis water. A lab-scale unit was built to implement the experiments and synthetic water (feed solution) was prepared with a known level of endotoxin (0.48 EU/mL). The test for Limulus amebocyte lysate was used to assess concentrations of endotoxin in treated water. The experimental results showed reduce of endotoxins in the cold plasma treatment. This type of treatment reduced the concentration of endotoxin to 0.17 ± 0.09 EU/ml. The results of the study indicated that this could be an innovation in cold plasma jet fields, with numerous applications in dialysis fluid preparation.
Показать больше [+] Меньше [-]Chemical Fraction and Health Effect of Size Segregate PM at National Highway of Northern India Полный текст
2023
Tiwari, Rahul | Botle, Akshay | Rajouriya, Kalpana | P Singh, Prabal | Taneja, Ajay
Sampling was conducted on Agra-Delhi national highway NH-2. Samples were collected with the help of Sioutas cascade impactor. During the sampling, PM1.0-0.5 (255.85µg/m3) was higher than PM2.5-1.0 (218.96µg/m3). The AQI value for the average PM2.5 concentration also exceeded the severe AQ limit (401-500). These results showed that PM2.5 pollution has a significant influence on the site as a result of a variety of anthropogenic activities. During the summer season, for PM1.0-0.5 and PM2.5-1.0 highest values (µg/m3) of metals followed the same trend and it was observed as Mg(6.52)> Ca(5.89)> Al(3.64)> while for PM2.5-1.0 it was as Mg(10.12)> Ca(9.5)> Al(5.95) respectively. At roadside, most of these metals are emitted from the resuspension of dust and vehicle activities which causes serious diseases to the human being. Cd, Cr, Cu, Pb, and Zn were highly enriched at national highway sampling sites, highlighting the crustal source, which has a major impact on metals concentration, followed by anthropogenic sources. The present research was conducted to find out the concentration level of metals in PM2.5-1.0 and PM1.0-0.5 particles in Agra, India to find out the health risk assessment at highway site.From the results, it was observed that all metals bound to larger size PM has high bioavailability. From the health risk assessment, it was found that all the metals bound smaller size particles showed higher HQ except in the case of Ni and Al. Cr, Pb showed carcinogenic risk to children and adults in both size fraction of PM except in the case of Ni.
Показать больше [+] Меньше [-]Optimized Zinc Uptake from the Aquatic Environment Using Biomass Derived from Lantana Camara L. Stem Полный текст
2023
Samimi, Mohsen | Nouri, Jafar
Biomass extracted from different plant parts can play a role as a cheap, efficient and eco-friendly adsorbent. In this research, Lantana Camara L. Stem biomass (LSB), a low-cost and useless material, was introduced as efficient biomass for divalent zinc biosorption from aqueous environments. For achieving optimal conditions in the zinc biosorption process, the experimental design was applied by the response surface methodology (RSM) based on a Box-Behnken design (BBD) model. Based on the comparison between the measured and predicted amounts, the values of R2,Radj2, and Rpred2 in the Zn(II) biosorption model were 0.9960, 0.9887 and 0.9441. The Zn(II) uptake in the experiments, BBD model-based (p-value of Lack-of-Fit term = 0.228 > 0.05), varied from 15.19% to 81.11%. The maximum analyte uptake at a LSB-to-Zn(II) ratio of 8:1, synthetic solution pH of 6.5 and residence time of 75 min was predicted at 97.12%. The maximum Z.R.% based on the validation test performed based on the optimal predicted conditions was also obtained at 94.65%, which is 2.5% different from the model's data amount, confirming the acceptable accuracy of the quadratic model. The LSB, in optimized conditions, as a low-cost biosorbent, can be a suitable candidate with acceptable potential for heavy metals biosorption from aquatic solutions.
Показать больше [+] Меньше [-]Effective combination of Lysinibacillus sphaericus and Phytoremediation in Soil Contaminated with Chromium Полный текст
2023
Nguyen Thanh, Hung | Nguyen Thi Ngoc, Ha | Mai Huong, Tra
In the framework of a project aiming to phytoremediate contaminated soils with heavy metal Cr in Long Khanh city, Dongnai province, Southeast of Vietnam, a series of greenhouse experiments followed by field trials were performed in order to evaluate the effect of L. sphaericus on the Cr phytoextraction by S. nigrum. The results showed that L. sphaericus improved the Cr uptake efficiency of S. nigrum through changing growth parameters such as root length, height, biomass and the ability to accumulate Cr in plants. At an application rate corresponding to the T3 treatment in this experiment, L. sphaericus can stimulate the dry biomass of S. nigrum by 143%, increase the Cr concentrations in the aerial part by 70%, the content of Cr extracted in a single plant up to 293% compared to treatment without L. sphaericus.
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