Enantioselective synthesis of the (1S,5R)-enantiomer of litseaverticillols A and B
2006
Morita, A.(Tohoku Univ., Sendai (Japan)) | Kiyota, H. | Kuwahara, S.
An enantioselective synthesis of the (1S,5R)-enantiomer of litseaverticillols A and B was accomplished in line with our previously reported synthetic pathway for their (1R,5S)-enantiomer. The use of 'EtSCeClsub(2)' prepared from EtSLi and CeClsub(3), instead of previously employed EtSLi itself, for the formation of thiol ester intermediates prevented any undesirable epimerization occurring in the process.
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书目信息
页码
pp. 2564-2566
其它主题
Synthese chimique; Sintesis quimica; Immunodeficience; Caractere acquis; Sesquiterpenoide
语言
英语
注释
Summary (En)
11 ref.
类型
Summary
2007-05-15
AGRIS AP