Enantiospecific synthesis from D-fructose of (2S,5R)- and (2R,5R)-2-methyl-1,6-dioxaspi-RO[4.5]decane [the odor bouquet minor components of Paravespula vulgaris (L.)].

Izquierdo Cubero I.; Lopez Espinosa M.T.P.; Richardson A.C.

Enantiospecific synthesis from D-fructose of (2S,5R)- and (2R,5R)-2-methyl-1,6-dioxaspi-RO[4.5]decane [the odor bouquet minor components of Paravespula vulgaris (L.)].

1993

Izquierdo Cubero I. | Lopez Espinosa M.T.P. | Richardson A.C.

The synthesis of (2S,5R)- (1) and (2R,5R)-2-methyl-1,6-dioxaspiro[4.5]decane (2) from (2RS,5R,8R,9R,10S)-8,9,10-trihydroxy-2-methyl-1,6 dioxaspiro[4.5]decane (8), obtained in five steps from D-fructose using Wittig's methodology, reduction, and spiroketalation, has been accomplished by a Corey dideoxygenation at C-8,9, followed by a Barton deoxygenation at C-10, of the appropriately protected derivatives.

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AGROVOC关键词

chemical composition chemical structure composition chimique feromonas fructosa fructose odeur olor pheromones smell structure chimique vespula

书目信息

发表于

Journal of chemical ecology

卷 19 ISSN 0098-0331

页码

v.1265-1283(6)

其它主题

Pheromone; Estructura quimica; Composicion quimica

语言

英语

注释

references. AVAILABILITY: US (DNAL QD415.A1J6).

类型

Journal Article

来源

Journal-of-chemical-ecology (USA). (Jun 1993). v. 19(6) p. 1265-1283.

自何时收录于AGRIS: 2012-11-15

格式: AGRIS AP

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Enantiospecific synthesis from D-fructose of (2S,5R)- and (2R,5R)-2-methyl-1,6-dioxaspi-RO[4.5]decane [the odor bouquet minor components of Paravespula vulgaris (L.)].

1993

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书目信息