Using a two site-reactive model for simulating one century changes of Zn and Pb concentration profiles in soils affected by metallurgical fallout

Mallmann , Fábio Joel Kochem
        . Departamento de Solos; Rheinheimer , Danilo dos Santos
        . Departamento de Solos; Labanowski , Jérôme
        . UMR 6008, LCME, Université de Poitiers-ESIP; Cambier , Philippe
        INRA
        , Versailles .
         UR 0251 Physico-chimie et Ecotoxicologie des Sols d'agrosystèmes contaminés; Lamy , Isabelle
        INRA
        , Versailles .
         UR 0251 Physico-chimie et Ecotoxicologie des Sols d'agrosystèmes contaminés; Santanna , Maria Alice
        . Departamento de Física; Tessier , Daniel
        INRA
        , Versailles .
         UR 0251 Physico-chimie et Ecotoxicologie des Sols d'agrosystèmes contaminés; Van Oort , Folkert
        INRA
        , Versailles .
         UR 0251 Physico-chimie et Ecotoxicologie des Sols d'agrosystèmes contaminés

Using a two site-reactive model for simulating one century changes of Zn and Pb concentration profiles in soils affected by metallurgical fallout

2012

Mallmann , Fábio Joel Kochem (Universidade Federal de Santa Maria, Santa Maria(Brésil). Departamento de Solos) | Rheinheimer , Danilo dos Santos (Universidade Federal de Santa Maria, Santa Maria(Brésil). Departamento de Solos) | Labanowski , Jérôme (Centre National de la Recherche Scientifique, Poitiers(France). UMR 6008, LCME, Université de Poitiers-ESIP) | Cambier , Philippe (INRA , Versailles (France). UR 0251 Physico-chimie et Ecotoxicologie des Sols d'agrosystèmes contaminés) | Lamy , Isabelle (INRA , Versailles (France). UR 0251 Physico-chimie et Ecotoxicologie des Sols d'agrosystèmes contaminés) | Santanna , Maria Alice (Universidade Federal de Santa Maria, Santa Maria(Brésil). Departamento de Física) | Tessier , Daniel (INRA , Versailles (France). UR 0251 Physico-chimie et Ecotoxicologie des Sols d'agrosystèmes contaminés) | Van Oort , Folkert (INRA , Versailles (France). UR 0251 Physico-chimie et Ecotoxicologie des Sols d'agrosystèmes contaminés)

Predicting the transfer of contaminants in soils is often hampered by lacking validation of mathematical models. Here, we applied Hydrus-2D software to three agricultural soils for simulating the 1900–2005 changes of zinc and lead concentration profiles derived from industrial atmospheric deposition, to validate the tested models with plausible assumptions on past metal inputs to reach the 2005 situation. The models were set with data from previous studies on the geochemical background, estimated temporal metal deposition, and the 2005 metal distributions. Different hypotheses of chemical reactions of metals with the soil solution were examined: 100% equilibrium or partial equilibrium, parameterized following kinetic chemical extractions. Finally, a two-site model with kinetic constant values adjusted at 1% of EDTA extraction parameters satisfactory predicted changes in metal concentration profiles for two arable soils. For a grassland soil however, this model showed limited applicability by ignoring the role of earthworm activity in metal incorporation.

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