[TcCl₄(H₂O)₂] and [Cl₃(H₂O)₂TcOTc(H₂O)₂Cl₃] – two molecular intermediates of the hydrolysis of technetium(iv)

Yegen, Eda; Hagenbach, Adelheid; Abram, Ulrich

[TcCl₄(H₂O)₂] and [Cl₃(H₂O)₂TcOTc(H₂O)₂Cl₃] – two molecular intermediates of the hydrolysis of technetium(iv)

2005

Yegen, Eda | Hagenbach, Adelheid | Abram, Ulrich

Two molecular intermediates of the hydrolysis of technetium tetrachloride, cis-[TcCl₄(H₂O)₂] and [Cl₃(H₂O)₂TcOTc(H₂O)₂Cl₃], were isolated and structurally characterised, suggesting that the hydrolytic degradation of technetium(iv) compounds occurs stepwise with the polymeric ‘TcO₂⋯nH₂O’ as a less defined final product.

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