Palladium-catalyzed desulfitative C–P coupling of arylsulfinate metal salts and H-phosphonates

Li, Junchen; Bi, Xiaojing; Wang, Hongmei; Xiao, Junhua

Palladium-catalyzed desulfitative C–P coupling of arylsulfinate metal salts and H-phosphonates

2014

Li, Junchen | Bi, Xiaojing | Wang, Hongmei | Xiao, Junhua

Catalyzed by palladium(ii) chloride, a diverse range of arylsulfinate sodium, potassium, lithium, silver, zinc, and copper salts undergo desulfination/C–P coupling with H-phosphonates, in the presence of silver(i) carbonate as oxidant, to produce useful arylphosphonates under microwave irradiation.

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