Determination of Hexaconazole in Surface Water Samples from River and the Sea by Liquid Chromatography-Electrospray Tandem Mass Spectrometry
2008
TSUKATANI, Hiroko | TOBIISHI, Kazuhiro | Tanaka, Yoshito | SAKURAGI, Kenji | IKEURA, Tasoh | NAKAMURA, Matayoshi
A simple and selective method was developed for determining the concentration of hexaconazole in river and sea water samples by using liquid chromatography/tandem mass spectrometry with an electrospray ionization interface in the positive ion mode and selective reaction monitoring mode. Trace amounts of hexaconazole were collected in a Sep-Pak Plus tC18 cartridge that was eluted with methanol. The detection limit for hexaconazole was 6 ng/l. The recovery of a standard aqueous solution containing 1 μg/l was 96%. The recovery of hexaconazole in the river and sea water samples was 95% and 90%, respectively. Hexaconazole was not detected in the sea water samples. Trace peaks of hexaconazole were found in the river water samples, the concentration being less than 6 ng/l in all cases. The biological degradation of hexaconazole was tested by using river water. No degradation of hexaconazole was apparent in river water incubated at 20 °C for 3 weeks.
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