Photodriven Clamlike Motion in a [3]Rotaxane with Two [2]Rotaxane Arms Bridged by an Overcrowded Alkene Switch
2013
Zhou, Wei | Guo, Ya-Jing | Qu, Da-Hui
A [3]rotaxane with two [2]rotaxane arms bridged by an overcrowded alkene switch has been constructed to perform the clamlike motion in response to light stimulus. We demonstrated that this [3]rotaxane can undergo reversible conformational changes caused by the trans–cis isomerizations of the central double bond with a favorable photostationary state (up to 90% conversion). It has been shown that the clamlike motion causes remarkable UV–vis and fluorescence spectral changes, allowing it to behave as a reversible optical molecular switch.
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书目信息
Journal of organic chemistry
卷
78
期
2
页码
590
- 596
ISSN
1520-6904
出版者
American Chemical Society
其它主题
Ultraviolet-visible spectroscopy; Organic chemistry
语言
英语
类型
Text; Journal Article
2024-02-27
MODS