Synthesis of Oxazoles by Tandem Cycloisomerization/Allylic Alkylation of Propargyl Amides with Allylic Alcohols: Zn(OTf)2 as π Acid and σ Acid Catalyst
2015
Wang, Bin | Chen, Ying | Zhou, Ling | Wang, Jianwu | Tung, Chen-Ho | Xu, Zhenghu
A Zn(OTf)₂-catalyzed tandem cycloisomerization/allylic alkylation of N-(propargyl)arylamides and allylic alcohols to produce oxazole derivatives has been successfully developed. The zinc catalyst served as π acid and also σ acid in this reaction. The target allylic oxazoles have been transformed into multisubstituted diene structures, which are potential aggregation-induced emission active optical materials.
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书目信息
出版者
American Chemical Society
其它主题
Oxazoles; Organic chemistry; Alkylation
语言
英语
类型
Journal Article; Text
2024-02-27
MODS