Heteromeric double helix formation by cross-hybridization of chloro-and fluoro-substituted quinoline oligoamides

Gan, Quan; Li, Fei; Li, Guoping; Kauffmann, Brice; Xiang, Junfeng; Huc, Ivan; Jiang, Hua

Heteromeric double helix formation by cross-hybridization of chloro-and fluoro-substituted quinoline oligoamides

2009

Oligoamides of 8-chloroquinoline have been synthesized and shown to assemble into double helical dimers both in solution and in the solid state, and to undergo cross-hybridization with 8-fluoroquinoline oligoamide analogues; the handedness of these double helices can be controlled via chiral residues.

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