Pd-Catalyzed kinetic resolution of cyclic enol ethers. An enantioselective route to functionalised pyrans

Zirimwabagabo, Jean-Olivier; Harrity, Joseph P. A.

Pd-Catalyzed kinetic resolution of cyclic enol ethers. An enantioselective route to functionalised pyrans

2014

Zirimwabagabo, Jean-Olivier | Harrity, Joseph P. A.

Functionalised cyclic enol ethers can be recovered with high levels of enantiocontrol after an asymmetric catalytic [1,3]-rearrangement reaction. These compounds can be further elaborated to a series of carbo- and heterocyclic products in good yield and with excellent levels of stereocontrol.

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