Difluoro(trimethylsilyl)acetonitrile: Synthesis and Fluoroalkylation Reactions
2012
Kosobokov, Mikhail D. | Dilman, Alexander D. | Levin, Vitalij V. | Struchkova, Marina I.
A new silicon reagent, difluoro(trimethylsilyl)acetonitrile, was prepared by insertion of difluorocarbene into silyl cyanide. The obtained silane served as a good cyanodifluoromethylating reagent toward aldehydes, N-tosylimines, N-alkylimines, and enamines under basic or acidic conditions.
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书目信息
Journal of organic chemistry
卷
77
期
13
页码
5850
- 5855
ISSN
1520-6904
出版者
American Chemical Society
其它主题
Acetonitrile; Silane; Organic chemistry; Enamines
语言
英语
类型
Journal Article; Text
2024-02-27
MODS
