Synthese und Kristallstruktur einer mit dem Johillerit verwandten Verbindung CdCu1,5Mg1,5Pb0,5O12 / Synthesis and Crystal Structure of a Johillerite Related Compound CdCu1,5Mg1,5Pb0,5O12
2014
Münchau, S. | Müller-Buschbaum, Hk
Single crystals of CdCu₁.₅Mg₁.₅Pb₀.₅V₃O₁₂ have been prepared in closed steel tubes using V₂O₅ as a flux. The orange crystals show monoclinic symmetry, space group C⁶₂ₕ-C2/c, a = 12.417(5), b = 12.983(6), c = 6.911(3) Å , β = 113.02(1)°, Z = 4. CdCu₁.₅Mg₁.₅Pb₀.₅V₃O₁₂ reveals a relationship to the Johillerite type, but it is characterized by an additional point position for cadmium, situated between the square planar CuO₄ polygons of the Johillerite structure.
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书目信息
出版者
Elsevier Science Ltd.
其它主题
Oxide; Crystals; Crystal structure; Crystal structure
语言
英语
类型
Journal Article; Text
2024-02-27
MODS