Orthoamide, LX [1]. N,N,N’,N’-Tetraformylhydrazin – ein breit anwendbares Formylierungsmittel für aromatische Verbindungen / Orthoamide, LX [1]. N,N,N’,N’-Tetraformylhydrazine – a Formylation Agent for Aromatic Compounds of Wide Scope
2014
Kantlehner, Willi | Haug, Erwin | Scherr, Oliver | Stoyanov, Edmont V. | Mezger, Jochen | Ziegler, Georg
The reagent system formed from N,N,N’,N’-tetraformylhydrazine (3) and aluminum chloride allows the formylation of aromatic compounds. The scope of the method is comparable with the Olah formylation and the Groß-Rieche procedure, since benzene and fluorobenzene can be formylated. Two formyl groups are transferred from 3 to the aromatic nuclei when a molar ratio 4:1:4 (aluminum chloride/3/aromatic compound) is chosen.
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书目信息
出版者
The Royal Society of Chemistry
其它主题
Aromatic aldehydes; N’; N’-tetraformylhydrazine; Formylation; Aluminum chloride; Electrophilic aromatic substitution; Moieties
语言
英语
类型
Journal Article; Text
2024-02-27
MODS