Practical and scalable preparation of 2-methyleneglutaronitrile via an efficient and highly selective head-to-tail dimerization of acrylonitrile catalysed by low-loading of tricyclohexylphosphine
2014
Yu, Lei | Wang, Jun | Zhang, Xu | Cao, Hongen | Wang, Genlin | Ding, Kehong | Xu, Qing | Lautens, M. (Mark)
By carefully evaluating the effect of solvent, ligand, temperature, and time, the commercially available tricyclohexylphosphine was found to be a particularly effective catalyst for head-to-tail dimerization of acrylonitrile, providing an efficient, scalable, and highly selective method for preparation of the useful 2-methyleneglutaronitrile with a low catalyst loading.
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书目信息
RSC advances
卷
4
期
37
页码
19122
- 19126
ISSN
2046-2069
出版者
The Royal Society of Chemistry
其它主题
Dimerization
语言
英语
类型
Journal Article; Text
2024-02-27
MODS