Electrochemical behaviour of uranium at a tripolyphosphate modified ITO electrode
2021
Hou, Xiangyang | McLachlan, Jeffrey R. | Dares, Christopher J.
UO₂²⁺ binds to the surface of a tripolyphosphate modified mesoporous indium tin-doped oxide electrode (nanoITO|P₃). Electrochemical studies reveal that nITO|P₃ electrodes catalyze the 2-electron interconversion between UO₂²⁺ and U⁴⁺ with the P₃-ligand assisting in the rate-limiting proton-coupled reduction of U(v) to U(iv), based on the kinetic isotope effect (1.8). Product composition between nITO|P₃(U⁴⁺) and surface adsorbed UO₂ can be controlled by adjusting the proton concentration and/or scan rate in voltammograms. These studies with uranium suggest that nITO|P₃ electrodes are good candidates for redox transformations with other actinides including neptunium, plutonium, and americium.
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