Iron-Catalyzed α-Methylation of Ketones Using Methanol as the C1 Source under Photoirradiation
2022
Emayavaramban, Balakumar | Chakraborty, Priyanka | Dahiya, Pardeep | Sundararaju, Basker
A mild, environmentally benign approach for α-methylation of ketones utilizing methanol as the C1 source under visible light has been developed. The reaction conditions were favorable for a wide range of ketones with both aromatic and aliphatic backbones, allowing for good-to-excellent yields of the respective products. The tentative mechanism is postulated after preliminary mechanistic and kinetic experiments.
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书目信息
Organic letters
卷
24
期
33
页码
6219
- 6223
ISSN
1523-7052
出版者
Elsevier Ltd
其它主题
Photoirradiation; Sustainable technology
语言
英语
类型
Journal Article; Text
2024-02-27
MODS