Inter-annual variation and comprehensive evaluation of organophosphate esters (OPEs) in the Yellow Sea, China
2022
Lin, Jianing | Zhang, Lutao | Guo, Changsheng | Feng, Song | Gao, Teng
Considering the extensive production and continuous usage of organophosphate esters (OPEs) around the urbanized coasts in recent years, the inter-annual variation and the ecological risks of OPEs in the Yellow Sea (YS), China were systematically evaluated in summer 2015 and 2019. The major component of OPEs, halogenated-OPEs in 78 surface and bottom seawater samples collected from 39 locations in the YS in 2019 were compared with 62 samples at 31 sites conducted in the same periods and similar stations in 2015. The average concentration of halogenated-OPEs increased 1.57, 2.50 folds in the surface and bottom seawater, respectively, in recent 5 years. The proportion of TCPP to halogenated-OPEs exhibited an increasing trend from 56.49% in 2015 to 79.95% in 2019. The peak values of halogenated-OPEs changed from the nearshore regions (33°N-38°N) in 2015 to the nearshore and offshore regions (33°N-35°N) in 2019, implying the growing terrigenous emission sources, especially some large OPEs producers nearby the coastal zones in the northern area of Jiangsu province. The targeted halogenated-OPEs posed no significant or low ecological risks to the aquatic organisms in 2015 and 2019, however, the values of RQ showed an elevated trend in 2019. Therefore, the ecological risks of OPEs in this region still need continuous concern due to the gradually increasing OPEs usage and production.
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