Dibenzoeilatin: a novel ligand exhibiting remarkable complementary π–π stacking interactions

Bergman, Sheba D.; Reshef, Dvora; Groysman, Stanislav; Goldberg, Israël; Kol, Moshe

Dibenzoeilatin: a novel ligand exhibiting remarkable complementary π–π stacking interactions

2002

Bergman, Sheba D. | Reshef, Dvora | Groysman, Stanislav | Goldberg, Israël | Kol, Moshe

The complex [Ru(bpy)₂(dbneil)][PF₆]₂ forms discrete dimers in solution held by strong π–π stacking interactions via its distorted dibenzoeilatin ligand, indicating that planarity is not an obligatory requirement for achieving strong π-stacking, as long as complementarity between the stacking moieties can be achieved.

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