A mild and efficient synthesis of new pentafluorosulfanyl-substituted electron-deficient alkenes and allylsilanes

Falkowska, Ewelina; Suzenet, Franck; Jubault, Philippe; Bouillon, Jean-Philippe; Pannecoucke, Xavier

A mild and efficient synthesis of new pentafluorosulfanyl-substituted electron-deficient alkenes and allylsilanes

2014

Falkowska, Ewelina | Suzenet, Franck | Jubault, Philippe | Bouillon, Jean-Philippe | Pannecoucke, Xavier

A series of pentafluorosulfanyl-substituted acrylic esters and amides have been synthesized in moderate to good yields from 3-pentafluorosulfanyl-prop-2-enol employing a chromic oxidation and subsequent coupling reaction. New pentafluorosulfanyl-substituted allylsilanes were also obtained from a SF5-Cl addition on allylsilanes followed by a β-elimination reaction.

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