100% thiol-functionalized ethylene PMOs prepared by “thiol acid–ene” chemistry
2013
Esquivel, Dolores | van den Berg, Otto | Romero-Salguero, Francisco J. | Du Prez, Filip | Van Der Voort, Pascal
A novel thiol functionalized bis-silane PMO precursor was synthesized by highly efficient thiol acid–ene chemistry between the double bonds of 1,2-(E)-bis(triethoxysilyl)ethene and thioacetic acid. After aminolysis the self-assembly process of the formed SH-precursor with Pluronic P123 under acidic conditions yields the first 100% thiol–PMO material with good structural ordering.
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书目信息
出版者
Elsevier Ltd
其它主题
Chemical bonding; Aminolysis; Chemical communication
语言
英语
类型
Journal Article; Text
2024-02-27
MODS